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Type HazMat fee for 500 gram (Estimated)
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Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 766-08-5 Chemical Structure| 766-08-5

Structure of 766-08-5

Chemical Structure| 766-08-5

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4.5 *For Research Use Only !

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Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

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Product Citations

Product Citations      Show More

Ewelina Szafoni ; Krzysztof Kuciński ; Grzegorz Hreczycho ;

Abstract: Cobalt complexes featuring triazine-based PNP ligands have proven to be exceptionally active and chemoselective pre-catalysts in facilitating the dehydrogenative coupling between silanes and amines, leading to the synthesis of diverse aminosilanes. Notably, even challenging substrates exhibited high reactivity. The catalyst‘s unique feature of avoiding coupling with tertiary silanes enhances process chemoselectivity. It facilitates a more precise synthesis of silylamines possessing of SiH2−N and SiH−N motifs, overcoming challenges associated with broader reactivity seen in previous systems. In terms of its remarkable chemoselectivity, it is also noteworthy that the catalytic system exhibits both versatility and efficacy in converting substrates with untouched double and triple carbon-carbon bonds. This accomplishment is particularly significant, given previous challenges brought about by the activity of commonly employed catalysts in the competitive hydrosilylation process.

Purchased from AmBeed: ;

Szafoni, Ewelina ; Kucinski, Krzysztof ; Hreczycho, Grzegorz ;

Abstract: Disclosed is a mild, scalable, and chemoselective cross-dehydrogenative functionalization protocol for the construction of Si−O−Si moieties under cobalt catalysis. The reaction has a broad scope and can be used to synthesize a wide range of silicon building blocks, including challenging dihydrosiloxanes and functionalized silsesquioxanes. Most importantly, the results are placed into context by benchmarking with state-of-the-art methods. Remarkably, the utilized PNP-Co catalyst enables the development of further synthetic strategies such as a one-pot sequential silanolysis/alcoholysis process or unprecedented dehydrocoupling reaction between germanol and hydrosilane.

Keywords: CobaltSilsesquioxanesSiloxanesSilanolsHydrosilanesDehydrogenative coupling

Purchased from AmBeed: ; ; ; ; ; ;

Alternative Products

Product Details of [ 766-08-5 ]

CAS No. :766-08-5
Formula : C7H10Si
M.W : 122.24
SMILES Code : C[SiH2]C1=CC=CC=C1
MDL No. :MFCD00039787
InChI Key :LAQFLZHBVPULPL-UHFFFAOYSA-N
Pubchem ID :6327655

Safety of [ 766-08-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338
Class:3
UN#:1993
Packing Group:

Application In Synthesis of [ 766-08-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 766-08-5 ]
  • Downstream synthetic route of [ 766-08-5 ]

[ 766-08-5 ] Synthesis Path-Upstream   1~4

  • 1
  • [ 766-08-5 ]
  • [ 546-45-2 ]
  • [ 77-63-4 ]
References: [1] Dalton Transactions, 2017, vol. 46, # 27, p. 8746 - 8750.
  • 2
  • [ 766-08-5 ]
  • [ 25015-63-8 ]
  • [ 546-45-2 ]
References: [1] Chemical Communications, 2017, vol. 53, # 72, p. 9998 - 10001.
  • 3
  • [ 766-08-5 ]
  • [ 6689-22-1 ]
  • [ 546-45-2 ]
  • [ 7110-06-7 ]
  • [ 142684-18-2 ]
References: [1] Journal of Organometallic Chemistry, 1992, vol. 428, # 3, p. 315 - 333.
  • 4
  • [ 4472-41-7 ]
  • [ 766-08-5 ]
  • [ 546-45-2 ]
  • [ 150730-19-1 ]
References: [1] Chemical Communications, 2014, vol. 50, # 94, p. 14820 - 14823.
 

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