[ CAS No. 76543-27-6 ] 1-Tosylazetidin-3-one

Cat. No.: A837759

2D 3D

Structure of 76543-27-6 * Storage: Sealed in dry,2-8°C

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98%	100mg	$18.00	Inquiry	Inquiry
98%	250mg	$26.00	Inquiry	Inquiry
98%	1g	$43.00	Inquiry	Inquiry
98%	5g	$105.00	Inquiry	Inquiry
98%	25g	$411.00	Inquiry	Inquiry

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* Storage: Sealed in dry,2-8°C

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Quality Control of [ 76543-27-6 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 76543-27-6 ]

Specification

Alternatived Products of [ 76543-27-6 ]

Product Details of [ 76543-27-6 ]

CAS No. :	76543-27-6	MDL No. :	MFCD00129860
Formula :	C₁₀H₁₁NO₃S	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	YRVBXEVVGIQJOZ-UHFFFAOYSA-N
M.W :	225.26	Pubchem ID :	535520
Synonyms :

Safety of [ 76543-27-6 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 76543-27-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 76543-27-6 ]

[ 76543-27-6 ] Synthesis Path-Downstream 1~13

1
[ 883909-30-6 ]
[ 76543-27-6 ]

Reference： [1]Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry,2005,vol. 44,p. 2560 - 2563

2
[ 76543-27-6 ]
2,7-bis-(toluene-4-sulfonyl)-9-oxa-2,7-diaza-dispiro[3.0.3.1]nonane [ No CAS ]

Reference： [1]Heterocycles,1998,vol. 49,p. 149 - 156

3
[ 76543-27-6 ]
[ 220332-12-7 ]

Reference： [1]Heterocycles,1998,vol. 49,p. 149 - 156

4
[ 56218-62-3 ]
copper (II)-complex of L-lysine [ No CAS ]
[ 76543-27-6 ]

Reference： [1]Journal of the Chemical Society. Perkin transactions I,1998,p. 1919 - 1923

5
[ 1080-44-0 ]
[ 76543-27-6 ]

Reference： [1]Journal of the Chemical Society. Perkin transactions I,1998,p. 1919 - 1923

6
[ 70-55-3 ]
[ 76543-27-6 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 1959 - 1964

7
[ 98-59-9 ]
sulfate diethylamine [ No CAS ]
[ 76543-27-6 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 1959 - 1964

8
[ 154010-95-4 ]
[ 76543-27-6 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 1959 - 1964
[2]Tetrahedron Letters,1993,vol. 34,p. 6677 - 6680

9
[ 154010-93-2 ]
[ 76543-27-6 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 1959 - 1964
[2]Tetrahedron Letters,1993,vol. 34,p. 6677 - 6680

10
[ 154010-94-3 ]
[ 76543-27-6 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 1959 - 1964
[2]Tetrahedron Letters,1993,vol. 34,p. 6677 - 6680

11
[ 98-59-9 ]
vinyldiacetonamine [ No CAS ]
[ 76543-27-6 ]

Reference： [1]Tetrahedron Letters,1993,vol. 34,p. 6677 - 6680

12
[ 56218-62-3 ]
[ 76543-27-6 ]

Reference： [1]Gazzetta Chimica Italiana,1985,vol. 115,p. 33 - 36
[2]Gazzetta Chimica Italiana,1985,vol. 115,p. 33 - 36

Yield	Reaction Conditions	Operation in experiment
		Filter and remove the ether in vacuo to obtain 2.0 g. of N-benzoyl-3-phenyl-3-azetidinol. By substituting equivalent quantities of: N-benzoyl-2-methyl-3-azetidinone, N-mesyl-2,4-dimethyl-3-azetidinone, N-tosyl-3-azetidinone, N-carbobenzyloxy-3-azetidinone, N-[γ,γ,γ-trifluoropropionyl]-2,4-diisopropyl-3-azetidinone, or N-benzoyl-2-ethyl-3-azetidinone

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Isomers

Technical Information

• Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Bucherer-Bergs Reaction • Clemmensen Reduction • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Fischer Indole Synthesis • Grignard Reaction • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Lawesson's Reagent • Leuckart-Wallach Reaction • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Aldehydes and Ketones • Preparation of Amines • Prins Reaction • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reformatsky Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Tebbe Olefination • Ugi Reaction • Wittig Reaction • Wolff-Kishner Reduction

Historical Records

Related Functional Groups of
[ 76543-27-6 ]

Aryls

[ 7730-45-2 ]

1-Tosylazetidine

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[ 73696-28-3 ]

1-Tosylpyrrolidin-3-one

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4-Methyl-N-(2-oxopropyl)benzenesulfonamide

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N-(3-Iodopropyl)-4-methyl-N-(2-oxoethyl)benzenesulfonamide

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N-(But-2-yn-1-yl)-4-methyl-N-(2-oxoethyl)benzenesulfonamide

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Ketones

[ 73696-28-3 ]

1-Tosylpyrrolidin-3-one

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[ 54972-26-8 ]

4-Methyl-N-(2-oxopropyl)benzenesulfonamide

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Sulfamides

[ 7730-45-2 ]

1-Tosylazetidine

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[ 73696-28-3 ]

1-Tosylpyrrolidin-3-one

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N-(3-Iodopropyl)-4-methyl-N-(2-oxoethyl)benzenesulfonamide

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[ 856409-63-7 ]

N-(But-2-yn-1-yl)-4-methyl-N-(2-oxoethyl)benzenesulfonamide

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Related Parent Nucleus of
[ 76543-27-6 ]

Azetidines

[ 7730-45-2 ]

1-Tosylazetidine

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[ 79201-18-6 ]

3,3-Dimethyl-1-tosylazetidine

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Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
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Response
Code	Phrase
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P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
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P311	Call a POISON CENTER or doctor/physician.
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P313	Get medical advice/attention.
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P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
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P332	IF SKIN irritation occurs:
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P337	If eye irritation persists:
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P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
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P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
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P378
P380	Evacuate area.
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P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
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P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
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P501	Dispose of contents/container to ...
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
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H204	Fire or projection hazard
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H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
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Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
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H310	Fatal in contact with skin
H311	Toxic in contact with skin
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Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 76543-27-6 ] 1-Tosylazetidin-3-one

Quality Control of [ 76543-27-6 ]

Related Doc. of [ 76543-27-6 ]

Product Details of [ 76543-27-6 ]

Safety of [ 76543-27-6 ]

Application In Synthesis of [ 76543-27-6 ]

[ 76543-27-6 ] Synthesis Path-Downstream 1~13

Technical Information

Related Functional Groups of [ 76543-27-6 ]

Aryls

Ketones

Sulfamides

Related Parent Nucleus of [ 76543-27-6 ]

Azetidines

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 76543-27-6 ]

Related Parent Nucleus of
[ 76543-27-6 ]