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Type HazMat fee for 500 gram (Estimated)
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Chemical Structure| 765-03-7 Chemical Structure| 765-03-7

Structure of 765-03-7

Chemical Structure| 765-03-7

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Product Details of [ 765-03-7 ]

CAS No. :765-03-7
Formula : C12H22
M.W : 166.30
SMILES Code : C#CCCCCCCCCCC
MDL No. :MFCD00008960

Safety of [ 765-03-7 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H318-H413
Precautionary Statements:P280-P305+P351+P338
Class:8
UN#:1760
Packing Group:

Application In Synthesis of [ 765-03-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 765-03-7 ]

[ 765-03-7 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 765-03-7 ]
  • [ 1186-73-8 ]
  • methyl 2,2-Di(methoxycarbonyl)tetradec-(E)-3-enoate [ No CAS ]
  • 2
  • [ 24134-09-6 ]
  • [ 765-03-7 ]
  • 5-(dodec-1-yn-1-yl)-1,2-dimethyl-1H-imidazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
164 mg With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; at 80℃; for 3h;Inert atmosphere; General procedure: To a solution of 2-disubstituted 1-methyl-1H-imidazole 1 (1 mmol) in DMF (5 mL), NBS(169 mg, 0,95 mmol) was added and the resulting reaction mixture was stirred in the dark at room temperature for 3h. Then, Pd(PPh3)2Cl2 (14 mg, 0.02 mmol, 2 mol%), CuI (8 mg, 0.04mmol, 4 mol%), an alkyne 3 (1,1 mmol) and piperidine (300 muL, 255 mg, 3 mmol) were added and the resulting reaction mixture was stirred at 80C (when trimethylsilylacetylene was employed as the alkyne, the reaction was carried out at 50C) for 3 h. The reaction mixture was diluted with EtOAc (100 mL), then saturated aqueous NH4Cl (100 mL) was added. The resulting mixture was stirred for 30 minutes and extracted with EtOAc (3x 25mL). The organic extracts were washed with water (3 x 25 mL) and brine (1 x 25 mL), driedover anhydrous Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by flash chromatogaraphy on silica gel. This procedure was employed to prepare compounds 4a-l. GLC analysis showed that all these compounds had chemical purity higherthan 98%.
  • 3
  • [ 1138-14-3 ]
  • [ 765-03-7 ]
  • 2-(dodec-1-en-3-yl)-1,3-di(thiophen-2-yl)propane-1,3-dione [ No CAS ]
 

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