Home Cart Sign in  
Chemical Structure| 74166-42-0 Chemical Structure| 74166-42-0

Structure of 74166-42-0

Chemical Structure| 74166-42-0

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 74166-42-0 ]

CAS No. :74166-42-0
Formula : C5H6OS2
M.W : 146.23
SMILES Code : O=S(C1=CC=CS1)C

Safety of [ 74166-42-0 ]

Application In Synthesis of [ 74166-42-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 74166-42-0 ]

[ 74166-42-0 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 5780-36-9 ]
  • [ 38695-60-2 ]
  • [ 74166-42-0 ]
  • 2
  • [ 74166-42-0 ]
  • [ 38695-60-2 ]
  • (+)-(R)-2-thienyl methyl sulfoxide [ No CAS ]
  • (R)-2-(methylsulfinyl)thiophene [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% With manganese(II) triflate; 1-Adamantanecarboxylic acid; C32H38N4O2; dihydrogen peroxide; In water; acetonitrile; at -30 - 20℃; for 0.5h;Inert atmosphere; Resolution of racemate; General procedure: Mn(OTf)2 (1.4 mg, 0.004 mmol) and L2 (2.0 mg, 0.004 mmol) were dissolved in acetonitrile, and the mixture was stirred at room temperature for 12 h. To the solution of manganese complex were added substrate (0.4 mmol), 0.2 equiv of aca (14.4 mg, 0.08 mmol), and 49 % aqeous hydrogen peroxide (56.5 mg, 0.4 mmol). Then decreased the temperature to -30 C, and the reaction mixture was stirred at -30 C for 0.5 h. The aqueous was separated, the organic layer was dried over MgSO4, filtered, concentrated at reduced pressure. The product was purified by silica gel column chromatography to afford the corresponding sulfoxide and sulfone.
 

Historical Records