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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
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Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 616-27-3 Chemical Structure| 616-27-3

Structure of 616-27-3

Chemical Structure| 616-27-3

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Product Details of [ 616-27-3 ]

CAS No. :616-27-3
Formula : C4H7ClO
M.W : 106.55
SMILES Code : CCC(CCl)=O
MDL No. :MFCD07368312
InChI Key :AALRHBLMAVGWRR-UHFFFAOYSA-N
Pubchem ID :69219

Safety of [ 616-27-3 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H226-H301-H311-H315-H319-H331-H335-H400
Precautionary Statements:P210-P240-P241-P242-P243-P261-P264-P270-P271-P273-P280-P302+P352-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P332+P313-P337+P313-P370+P378-P391-P403+P233-P403+P235-P405-P501
Class:6.1(3)
UN#:2929
Packing Group:

Application In Synthesis of [ 616-27-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 616-27-3 ]

[ 616-27-3 ] Synthesis Path-Downstream   1~12

  • 1
  • [ 67-56-1 ]
  • [ 590-29-4 ]
  • [ 616-27-3 ]
  • [ 5077-67-8 ]
  • 2
  • [ 590-29-4 ]
  • [ 616-27-3 ]
  • [ 5077-67-8 ]
  • 3
  • [ 616-27-3 ]
  • [ 513-86-0 ]
  • [ 5077-67-8 ]
  • 5
  • [ 616-27-3 ]
  • [ 5077-67-8 ]
  • [ 79-31-2 ]
  • 6
  • [ 7732-18-5 ]
  • [ 616-27-3 ]
  • lead (II)-oxide [ No CAS ]
  • [ 513-86-0 ]
  • [ 5077-67-8 ]
  • 7
  • [ 616-27-3 ]
  • Pb(OH)2 [ No CAS ]
  • [ 513-86-0 ]
  • [ 5077-67-8 ]
  • 8
  • [ 616-27-3 ]
  • Pb(OH)2 [ No CAS ]
  • KOH (5 percent ) [ No CAS ]
  • [ 513-86-0 ]
  • [ 5077-67-8 ]
  • 9
  • [ 616-27-3 ]
  • NaHCO3 [ No CAS ]
  • [ 5077-67-8 ]
  • [ 79-31-2 ]
References: [1]Patent: FR796008, .
  • 10
  • [ 616-27-3 ]
  • natrium carbonate [ No CAS ]
  • [ 5077-67-8 ]
  • [ 79-31-2 ]
References: [1]Patent: FR796008, .
  • 11
  • [ 26189-59-3 ]
  • [ 5077-67-8 ]
  • C9H18NO2(1+)*Cl(1-) [ No CAS ]
  • [ 616-27-3 ]
YieldReaction ConditionsOperation in experiment
65% In dichloromethane; at 20℃; for 1h;Inert atmosphere; Procedure A: 0.567 g (6.4 mmol) of 22a, 0.945 g (7.67 mmol) 2a, 7 mL CH2Cl2, 1 hat rt; ratio 4.6/1 1-chloro-2-butanone 23a/iminium salt 24a measured by 1H NMR. 1-Chloro-2-butanone 23a 0.445 g (65percent) was purified by distillation (30 °C/13 mmHg) and was found identicalwith an authentic sample: 1H NMR (200 MHz, CDCl3): 4.12 (s, 2H), 2.63 (q, J=7.3 Hz, 2H), 1.12 (t, J=7.3 Hz, 3H). The minor product 24a was not purified. The structure was proposed on the basis of its 1H NMR spectrum and the comparison with the spectroscopic properties of 24b-d. 1H NMR (200 MHz, CDCl3): 4.97 (d, J=9.7 Hz, 1H), 4.71 (d, J=9.7 Hz, 1H), 3.61 (s, 3H), 3.50 (s, 3H), 1.68 (s, 3H), 1.44 (q, J=7.3 Hz, 2H), 1.43 (s, 3H), 1.09 (t, J=7.3 Hz, 3H).
  • 12
  • [ 10365-98-7 ]
  • [ 616-27-3 ]
  • [ 35553-92-5 ]
 

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