There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
Structure of 616-27-3
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The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
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Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 616-27-3 |
Formula : | C4H7ClO |
M.W : | 106.55 |
SMILES Code : | CCC(CCl)=O |
MDL No. : | MFCD07368312 |
InChI Key : | AALRHBLMAVGWRR-UHFFFAOYSA-N |
Pubchem ID : | 69219 |
GHS Pictogram: |
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Signal Word: | Danger |
Hazard Statements: | H226-H301-H311-H315-H319-H331-H335-H400 |
Precautionary Statements: | P210-P240-P241-P242-P243-P261-P264-P270-P271-P273-P280-P302+P352-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P332+P313-P337+P313-P370+P378-P391-P403+P233-P403+P235-P405-P501 |
Class: | 6.1(3) |
UN#: | 2929 |
Packing Group: | Ⅱ |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | In dichloromethane; at 20℃; for 1h;Inert atmosphere; | Procedure A: 0.567 g (6.4 mmol) of 22a, 0.945 g (7.67 mmol) 2a, 7 mL CH2Cl2, 1 hat rt; ratio 4.6/1 1-chloro-2-butanone 23a/iminium salt 24a measured by 1H NMR. 1-Chloro-2-butanone 23a 0.445 g (65percent) was purified by distillation (30 °C/13 mmHg) and was found identicalwith an authentic sample: 1H NMR (200 MHz, CDCl3): 4.12 (s, 2H), 2.63 (q, J=7.3 Hz, 2H), 1.12 (t, J=7.3 Hz, 3H). The minor product 24a was not purified. The structure was proposed on the basis of its 1H NMR spectrum and the comparison with the spectroscopic properties of 24b-d. 1H NMR (200 MHz, CDCl3): 4.97 (d, J=9.7 Hz, 1H), 4.71 (d, J=9.7 Hz, 1H), 3.61 (s, 3H), 3.50 (s, 3H), 1.68 (s, 3H), 1.44 (q, J=7.3 Hz, 2H), 1.43 (s, 3H), 1.09 (t, J=7.3 Hz, 3H). |