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Chemical Structure| 603122-81-2 Chemical Structure| 603122-81-2

Structure of 603122-81-2

Chemical Structure| 603122-81-2

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Product Details of [ 603122-81-2 ]

CAS No. :603122-81-2
Formula : C9H11BO4
M.W : 193.99
SMILES Code : CC1=CC(B(O)O)=CC=C1C(OC)=O
MDL No. :MFCD18432535
InChI Key :JAVZEYJXDZSLOV-UHFFFAOYSA-N
Pubchem ID :22171598

Safety of [ 603122-81-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P261-P280-P305+P351+P338-P304+P340

Application In Synthesis of [ 603122-81-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 603122-81-2 ]

[ 603122-81-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 525362-07-6 ]
  • [ 603122-81-2 ]
YieldReaction ConditionsOperation in experiment
71.2% With sodium periodate; ammonium acetate; In water; acetone; at 20℃; for 16h; A mixture of methyl 2-methyl-4-(4,4,5 ,5-tetramethyl- 1,3 ,2-dioxaborolan-2- yl)benzoate (400.0 mg, 1.45 mmol) , sodium periodate (309.8 mg, 1.45 mmol) and ammoniumacetate (800.0 mg, 10.38 mmol) in acetone (8 mL) and water (4 mL) was stirred at 20 C for 16 h, and evaporated to dryness. The residue was taken up in EtOAc (20 mL), washed with water (20 mL x 2) and brine (20 mL), dried over Mg504 and concentrated. The residue was purified by flash column chromatography (33% ethyl acetate in petroleum ether) to afford (4- methoxycarbonyl-3-methyl-phenyl)boronic acid (200 mg, 71.2% yield) as a white solid.
 

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Technical Information

• Acyl Group Substitution • Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Benzylic Oxidation • Birch Reduction • Blanc Chloromethylation • Bouveault-Blanc Reduction • Bucherer-Bergs Reaction • Catalytic Hydrogenation • Clemmensen Reduction • Complex Metal Hydride Reductions • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Ester Cleavage • Fischer Indole Synthesis • Friedel-Crafts Reaction • Grignard Reaction • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Hydrogenolysis of Benzyl Ether • Lawesson's Reagent • Leuckart-Wallach Reaction • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Aldehydes and Ketones • Preparation of Alkylbenzene • Preparation of Amines • Prins Reaction • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions with Organometallic Reagents • Reformatsky Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Specialized Acylation Reagents-Carbodiimides and Related Reagents • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Tebbe Olefination • Ugi Reaction • Vilsmeier-Haack Reaction • Wittig Reaction • Wolff-Kishner Reduction

Categories

Related Functional Groups of
[ 603122-81-2 ]

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