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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 59795-89-0 Chemical Structure| 59795-89-0

Structure of 59795-89-0

Chemical Structure| 59795-89-0

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Product Details of [ 59795-89-0 ]

CAS No. :59795-89-0
Formula : C9H9N
M.W : 131.17
SMILES Code : [C-]#[N+]CCC1=CC=CC=C1
MDL No. :MFCD02664670
InChI Key :XIJXCJCWHKUKAW-UHFFFAOYSA-N
Pubchem ID :427710

Safety of [ 59795-89-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H311-H315-H319-H331-H335
Precautionary Statements:P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P330-P332+P313-P337+P313-P361-P403+P233-P405-P501
Class:6.1
UN#:2810
Packing Group:

Application In Synthesis of [ 59795-89-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 59795-89-0 ]

[ 59795-89-0 ] Synthesis Path-Downstream   1~10

  • 1
  • [ 23069-99-0 ]
  • [ 59795-89-0 ]
YieldReaction ConditionsOperation in experiment
With triethylamine; triphenylphosphine; In tetrachloromethane; dichloromethane; for 4h;Reflux; Inert atmosphere; General procedure: The respective amine (4 mmol, 1 eq) and ethyl formate (4.4 mmol, 1.1 eq) are refluxed for 3 h. After 5 min of evaporation of the volatile reaction products by opening the reaction apparatus, 10 ml of dry DCM are added as well as PPh3 (4.8 mmol, 1.2 eq), NEt3 (4 mmol, 1 eq) and CCl4 (4 mmol,1 eq). The apparatus is charged with argon and the mixture refluxed for 4 h. After cooling to room temperature, a premixed solution (30 min) of 10 ml dry methanol, the respective 2-aminopyridine (2 mmol, 0.5 eq), aldehyde (2 mmol, 0.5 eq) and glacial acetic acid (6 mmol, 1.5 eq) is added. After 48h at 40 C the formation of imidazo[1,2-a]pyridine is controlled by TLC and several grams of silica gel are added to the reaction mixture. After evaporating to dryness on a rotavapor, the loaded silica gel is worked up by column chromatography (hexane/ethyl acetate 10:1, 5:1, 3:1 and 1:1) to furnish the desired product.
  • 2
  • [ 50-00-0 ]
  • [ 1240361-06-1 ]
  • [ 5680-79-5 ]
  • [ 59795-89-0 ]
  • C27H35N3O6S [ No CAS ]
  • 3
  • [ 1191-95-3 ]
  • [ 32161-30-1 ]
  • [ 59795-89-0 ]
  • [ 22483-09-6 ]
  • C28H39N3O6 [ No CAS ]
  • 4
  • [ 29943-42-8 ]
  • [ 32161-30-1 ]
  • [ 59795-89-0 ]
  • [ 22483-09-6 ]
  • C29H41N3O7 [ No CAS ]
  • 5
  • [ 29943-42-8 ]
  • [ 32161-30-1 ]
  • [ 59795-89-0 ]
  • 4-((5S)-8,9-dimethoxy-4-oxo-1,2,3,4,5,6-hexahydro-1,5-epiminobenzo[d]azocin-11-yl)-N-phenethyltetrahydro-2H-pyran-4-carboxamide [ No CAS ]
  • 6
  • [ 32161-30-1 ]
  • [ 59795-89-0 ]
  • 1-((5S)-8,9-dimethoxy-4-oxo-1,2,3,4,5,6-hexahydro-1,5-epiminobenzo[d]azocin-11-yl)-Nphenethylcyclobutanecarboxamide [ No CAS ]
  • 7
  • [ 59795-89-0 ]
  • [ 122-78-1 ]
  • [ 13850-91-4 ]
  • [ 74-89-5 ]
  • C29H41N3O4 [ No CAS ]
  • C29H41N3O4 [ No CAS ]
  • 8
  • [ 21109-25-1 ]
  • [ 51673-84-8 ]
  • [ 59795-89-0 ]
  • [ 65-85-0 ]
  • C29H31N3O4 [ No CAS ]
  • 9
  • [ 21109-25-1 ]
  • [ 59795-89-0 ]
  • [ 78538-75-7 ]
  • 10
  • [ 70-18-8 ]
  • [ 59795-89-0 ]
  • [ 23069-99-0 ]
  • C19H26N4O6S [ No CAS ]
 

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