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Chemical Structure| 59083-33-9 Chemical Structure| 59083-33-9

Structure of 59083-33-9

Chemical Structure| 59083-33-9

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Product Details of [ 59083-33-9 ]

CAS No. :59083-33-9
Formula : C8H10OS
M.W : 154.23
SMILES Code : OCC1=CC=CC(SC)=C1
MDL No. :MFCD11113493

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Application In Synthesis of [ 59083-33-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 59083-33-9 ]

[ 59083-33-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 59083-33-9 ]
  • [ 220798-39-0 ]
YieldReaction ConditionsOperation in experiment
With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20℃; To a 0 C solution of (3-methanesulfanyl-phenyl)-methanol (4.57 g, 30 mmol) in dichloromethane (100 ml_) was added m-chloroperoxybenzoic acid (16 g, 93 mmol), in portions over the course of 1 hour. The reaction mixture was allowed to warm to room temperature, then stirred for 24 hours. The reaction mixture was washed with a saturated aqueous solution of sodium sulfite followed by a saturated aqueous solution of sodium bicarbonate. The organic phase was dried over Na2SO4, filtered, and evaporated. Flash chromatography (Analogix SuperFlash column, 35% - 50% ethyl acetate in hexanes) gave 2.68 g (49% over three steps) of (3-methanesulfonyl- phenyl)-methanol as a white solid.
 

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