58929-72-9|1-Bromo-3-(3-bromopropoxy)propane| Ambeed

Size	Price	VIP Price	US Stock	Global Stock	In Stock
{[ item.pr_size ]}		Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

{[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

Quality Control of [ 58929-72-9 ] Purity: 95% SDS Specification

COA

Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.

NMR

Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.

CNMR

Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.

HPLC

Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.

LC-MS

Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.

1-2 Day Shipping
High Quality
Technical Support

Product Details of [ 58929-72-9 ]

CAS No. :	58929-72-9
Formula :	C₆H₁₂Br₂O
M.W :	259.97
SMILES Code :	BrCCCOCCCBr
MDL No. :	MFCD22200244
InChI Key :	GOKUDEWVRNZXDZ-UHFFFAOYSA-N
Pubchem ID :	11230705

Safety of [ 58929-72-9 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 58929-72-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 58929-72-9 ]

[ 58929-72-9 ] Synthesis Path-Downstream 1~35

1
[ 110-89-4 ]
[ 58929-72-9 ]
[ 110129-10-7 ]

References: [1]Journal Of Scientific and Industrial Research,1953,vol. 12B,p. 532,533,534.

2
[ 635-46-1 ]
[ 58929-72-9 ]
bis-[3-(3,4-dihydro-2<i>H</i>-[1]quinolyl)-propyl]-ether [ No CAS ]

References: [1]Journal Of Scientific and Industrial Research,1953,vol. 12B,p. 532,533,534.

3
[ 58929-72-9 ]
[ 128-44-9 ]
1,1,1',1'-tetraoxo-2,2'-(4-oxa-heptanediyl)-bis-1λ⁶-benz[<i>d</i>]isothiazol-3-one [ No CAS ]

References: [1]Journal of the American Chemical Society,1955,vol. 77,p. 5628.

4
[ 58929-72-9 ]
[ 109-89-7 ]
[ 108012-94-8 ]

References: [1]Journal Of Scientific and Industrial Research,1953,vol. 12B,p. 532,533,534.

5
[ 58929-72-9 ]
[ 75-50-3 ]
[ 108876-24-0 ]

References: [1]Journal de Pharmacie de Belgique,1952,vol. 7,p. 295,298,304.

6
[ 504-63-2 ]
[ 58929-72-9 ]

References: [1]Patent: WO2005/68410,2005,A1 .Location in patent: Page/Page column 232.
[2]Journal of the American Chemical Society,1921,vol. 43,p. 2229.

7
[ 2396-61-4 ]
[ 58929-72-9 ]

Yield	Reaction Conditions	Operation in experiment
55%	With phosphorus tribromide; at 20℃;Heating / reflux;Product distribution / selectivity;	6.2 EXAMPLES OF ILLUSTRATIVE COMPOUNDS OF THE INVENTION; Bis (3-bromopropyl) ether (104).; Under N2-atmosphere, phosphorus tribromide (7.2 mL, 20.5 g, 75.8 mmol) was added dropwise over 1 h to 103 (Buchanan, G. W. et al. Can. J Chem. 2000, 78, 316-321) (10.14 g, 75.6 mmol), causing self-heating to reflux. The reaction mixture was stirred overnight at room temperature, then distilled in vacuo to give an oil. This oil was dissolved in CH2C12 (100 mL), washed with water (100 mL), dried over Na2SO4, and concentrated in vacuo, affording 104 (10.9 g, 55 %) as a clear, colorless oil. Bp 68-70 C/0. 2 mmHg. 1H NMR (CDC13) : No. 3.56 (t, 4 H, J= 5.8), 3.51 (t, 4 H, J= 6.4), 2.10 (m, 4 H). 13C NMR (CDC13 = 77. 00 ppm) : 6 68. 17,32. 68,30. 59.
34%	With phosphorus tribromide; at 20 - 90℃;	To a flask containing compound 2 (11 g, 82.0 mmol), PBr3 (55 mL) was added slowly drop wise and the mixture stirred for 0.5 hours at ambient temperature followed by heating to 900C. After being stirred for 3 hours at this temperature the reaction mixture was quenched with ice (500 g) slowly, stirred continuously for 10 minutes and extracted with CH2Cl2 (2 X 700 mL). The organic layer was dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure to give compound 3 as a pale yellow liquid (7.24 g). Yield: 34%. 1HNMR (400 MHz, CDCl3): δ (ppm): 3.70-3.55 (t, 4H), 3.60-3.35 (t, 4H), 2.15-1.95 (m, 4H).

References: [1]Journal of Medicinal Chemistry,2004,vol. 47,p. 5183 - 5197.
[2]Patent: WO2005/68410,2005,A1 .Location in patent: Page/Page column 232; 240.
[3]Patent: WO2010/139966,2010,A1 .Location in patent: Page/Page column 109-110.
[4]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.
[5]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

8
[ 58929-72-9 ]
(2-Methoxy-ethyl)-(2-phenoxy-ethyl)-amine [ No CAS ]
(2-Methoxy-ethyl)-(3-{3-[(2-methoxy-ethyl)-(2-phenoxy-ethyl)-amino]-propoxy}-propyl)-(2-phenoxy-ethyl)-amine [ No CAS ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

9
[ 58929-72-9 ]
(2-Methoxy-ethyl)-[2-(naphthalen-2-yloxy)-ethyl]-amine [ No CAS ]
(2-Methoxy-ethyl)-[3-(3-{(2-methoxy-ethyl)-[2-(naphthalen-2-yloxy)-ethyl]-amino}-propoxy)-propyl]-[2-(naphthalen-2-yloxy)-ethyl]-amine [ No CAS ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

10
[ 58929-72-9 ]
[2-(4-Chloro-phenoxy)-ethyl]-(2-methoxy-ethyl)-amine [ No CAS ]
[ 58929-39-8 ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

11
[ 58929-72-9 ]
[3-(4-Chloro-phenoxy)-propyl]-(2-methoxy-ethyl)-amine [ No CAS ]
[ 58929-41-2 ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

12
[ 58929-72-9 ]
[2-(2-Chloro-phenoxy)-ethyl]-(2-methoxy-ethyl)-amine [ No CAS ]
[ 58929-37-6 ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

13
[ 58929-72-9 ]
[ 75-07-0 ]
[ 6607-56-3 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

14
[ 58929-72-9 ]
[ 123-38-6 ]
[ 6607-57-4 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

15
[ 58929-72-9 ]
[ 123-72-8 ]
[ 6607-60-9 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

16
[ 58929-72-9 ]
[ 78-84-2 ]
[ 6607-58-5 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

17
[ 58929-72-9 ]
[ 67-64-1 ]
[ 6607-59-6 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1963,vol. 20,p. 14 - 19.

18
[ 58929-72-9 ]
[ 109-85-3 ]
[ 58929-78-5 ]

References: [1]Arzneimittel-Forschung/Drug Research,1975,vol. 25,p. 1853 - 1858.

19
[ 58929-72-9 ]
[ 88420-24-0 ]
[ 88420-46-6 ]

Yield	Reaction Conditions	Operation in experiment
47%	With potassium carbonate; In N-methyl-acetamide; acetone;	EXAMPLE 56 Preparation of [4-acetyl-3-[3-(3-bromopropoxy)propoxy]-2-propylphenoxy]acetic acid ethyl ester A mixture of 2.5 g (0.0089 mole) of (4-acetyl-3-hydroxy-2-propylphenoxy)acetic acid ethyl ester, 11.6 g (0.045 mole) of 3,3'-dibromodipropyl ether, 1.0 g (0.0072 mole) of potassium carbonate in 50 ml of anhydrous acetone and 25 ml of anhydrous dimethylformamide was stirred at reflux for 66 hours. Additional 1.0 g portions of potassium carbonate were added after 6,18,26 and 42 hours. The reaction mixture was filtered and the filtrate was concentrated in vacuo to yield an oil which was chromatographed on 125 g of silica gel. Elution with 10% ethyl acetate-toluene gave 1.9 g (47% yield) of [4-acetyl-3-[3-(3-bromopropoxy)propoxy]-2-propylphenoxy]acetic acid ethyl ester as an oil.

References: [1]Patent: US4507498,1985,A .
[2]Journal of Medicinal Chemistry,1987,vol. 30,p. 173 - 178.

20
[ 58929-72-9 ]
[ 88420-31-9 ]
[ 88420-47-7 ]

Yield	Reaction Conditions	Operation in experiment
55%	With potassium carbonate; In N-methyl-acetamide; acetone;	EXAMPLE 59 Preparation of 4-[4-acetyl-3-[3-(3-bromopropoxy)propoxy]-2-propylphenoxy]butanoic acid ethyl ester A mixture of 2.5 g (0.008 mole) of 4-(4-acetyl-3-hydroxy-2-propylphenoxy)butanoic acid ethyl ester, 10.6 g (0.041 mole) of 3,3'-dibromodipropyl ether and 1.0 g (0.0072 mole) of potassium carbonate in 50 ml of anhydrous acetone and 25 ml of anhydrous dimethylformamide was stirred at reflux for 66 hours. Additional 1.0 g portions of potassium carbonate were added at 6, 18, 26 and 42 hours. The reaction mixture was filtered and the filtrate was concentrated in vacuo to yield an oil which was chromatographed on 150 g of silica gel. Elution with 7% ethyl acetate-toluene gave 2.16 g (55% yield) of 4-[4-acetyl-3-[3-(3-bromopropoxy)propoxy]-2-propylphenoxy]butanoic acid ethyl ester as an oil.

References: [1]Patent: US4507498,1985,A .
[2]Journal of Medicinal Chemistry,1987,vol. 30,p. 173 - 178.

21
[ 58929-72-9 ]
[ 79-31-2 ]
[ 171510-89-7 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

22
[ 7664-93-9 ]
[ 12258-64-9 ]
[ 504-63-2 ]
[ 58929-72-9 ]
[ 109-64-8 ]
[ 627-18-9 ]

References: [1]Journal of the American Chemical Society,1921,vol. 43,p. 2229.

23
[ 136-95-8 ]
[ 627-18-9 ]
[ 58929-72-9 ]
2-imino-3-(γ-hydroxypropyl)benzothiazoline [ No CAS ]
bis[3-(γ-hydroxypropyl)benzothiazol-2-ylidene]ammonium bromide [ No CAS ]

References: [1]Chemistry of Heterocyclic Compounds,1999,vol. 35,p. 860 - 865.

24
[ 58929-72-9 ]
[ 97-62-1 ]
[ 183293-87-0 ]

Yield	Reaction Conditions	Operation in experiment
69%	With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; concd HCl; lithium diisopropyl amide; In tetrahydrofuran; n-heptane;	5-(4-Ethoxycarbonyl-4-methylpentyloxy)-2,2-dimethylpentanoic acid ethyl ester (106). Under nitrogen atmosphere and at -78 C., to a stirred solution of ethyl isobutyrate (6.5 g, 55.9 mmol) in anhydrous THF (30 mL) was added dropwise a solution of lithium diisopropylamide (30 mL, 60.0 mmol, 2.0 M in heptane/THF/ethylbenzene). After 1 h, a solution of 104 (Kamm, O. et al. J. Am. Chem. Soc. 1921, 43, 2228-2230) (6.76 g, 26.0 mmol) and DMPU (2 mL) in THF (15 mL) was added dropwise and the reaction temperature was kept at -78 C. for additional 30 min. The reaction mixture was allowed to warn to room temperature and stirred overnight, then quenched with a mixture of ice (10 g) and concd HCl (10 mL). The product was extracted with diethyl ether (2*30 mL). The combined ether phases were washed with 5% NaHCO3 solution (30 mL), dried over MgSO4, and concentrated in vacuo to furnish the crude product (10.9 g), which was distilled in high vacuo to give pure 106 (5.96 g, 69%) as an oil. Bp 115-120 C./0.5 mmHg. 1H NMR (CDCl3): δ 4.11 (q, 4H, J=7.0), 3.37 (m, 4H), 1.62-1.43 (m, 8H), 1.25 (t, 4H, J=7.0), 1.17 (s, 12H). 13C NMR (CDCl3=77.00 ppm): δ 177.62, 70.85, 60.06, 41.75, 36.89, 25.14, 24.96, 14.09.
69%		5- (4-Ethoxycarbonyl-4-methylpentyloxy)-2, 2-dimethylpentanoic acid ethyl ester (106).; Under nitrogen atmosphere and at-78 C, to a stirred solution of ethyl isobutyrate (6.5 g, 55.9 mmol) in anhydrous THF (30 mL) was added dropwise a solution of lithium diisopropylamide (30 mL, 60.0 mmol, 2.0 M in heptane/THF/ethylbenzene). After 1 h, a solution of 104 (Kamm, O. et al. J. Am. Chem. Soc. 1921, 43, 2228-2230) (6.76 g, 26.0 mmol) and DMPU (2 mL) in THF (15 mL) was added dropwise and the reaction temperature was kept at-78 C for additional 30 min. The reaction mixture was allowed to warm to room temperature and stirred overnight, then quenched with a mixture of ice (10 g) and concd HCl (10 mL). The product was extracted with diethyl ether (2 x 30 mL). The combined ether phases were washed with 5 % NaHC03 solution (30 mL), dried over M 4S encEnthatYeivacuo to furnish the crude product (10. Y g), which was distilled in high vacuo to give pure 106 (5.96 g, 69 %) as an oil. Bp 115-120 C/0. 5 mmHg. lH NMR (CDCl3) : 8 4.11 (q, 4 H, J= 7. 0j, 3.37 (m, 4 H), 1. 62-1.43 (m, 8 H), 1.25 (t, 4 H, J= 7.0), 1.17 (s, 12 H). 13C NMR (CDC13 = 77.00 ppm): 5 177.62, 70.85, 60.06, 41.75, 36. 89, 25. 14, 24.96, 14.09.

References: [1]Journal of Medicinal Chemistry,2004,vol. 47,p. 5183 - 5197.
[2]Patent: US2004/192771,2004,A1 .
[3]Patent: WO2005/68410,2005,A1 .Location in patent: Page/Page column 232; 240-241.

25
[ 58929-72-9 ]
[ 2510-99-8 ]
[ 765284-31-9 ]

Yield	Reaction Conditions	Operation in experiment
27%		5- (4-Ethoxycarbonyl-4-phenylpentyloxy)-2-methyl-2-phenylpentanoic acid ethyl ester (107).; Under Na-atmosphere, to a stirred solution of 2-phenylpropionic acid ethyl ester (Dasseux, J. -L. H. et al. US 20030078239,2003 ; US Pat. Appl. 09/976,938, filed October 11, 2001) (13.2 g, 74.1 mmol) in anhydrous THF (50 mL) was added dropwise a solution of lithium diisopropylamide (39 mL, 78. 0 mmol, 2.0 M in heptane/THF/ethylbenzene) at- 78 C. After 1 h, DMPU (3 mL) was added, followed by the dropwise addition of a solution of 104 (9.2 g, 35.4 mmol) in THF (20 mL). After 30 min at-78 C, the reaction mixture was warmed to room temperature and stirred overnight. The reaction mixture was poured into a mixture of ice (30 g) and concd HCl (20 mL) and the product was extracted with diethyl ether (4 x 75 mL). The combined ether solutions were washed with 5 % NaHC03 solution (50 mL), and brine (50 mL), dried over MgS04, and concentrated in vacuo to furnish the crude product (18.9 g) as a brown oil. Purification by column chromatography (silica; hexanes/ethyl acetate = 10/1) gave 7 (4.3 g, 27 %) as a yellow oil. 'H NMR (CDC13) : 8 7.45-7. 10 (m, 10 H), 4.11 (q, 4 H, J = 7.2), 3.45-3. 25 (m, 4 H), . 2. 15-1.85 (m, 4 H), 1.54 (s, 6 H), 1.50-1. 35 (m, 4 H), 1.17 (t, 6 H, J= 7. 2). 13C NMR (CDCl3 = 77.00 ppm): 8 176.00, 143.71, 128.23, 126.50, 125.90, 70.89, 60.66, 49.86, 35.66, 25.08, 22.66, 14.02. HRMS (LSIMS, nba): Calcd for C28H390s (ME+) : 455.2797, found : 455.2796.
	With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; concd HCl; lithium diisopropyl amide; In tetrahydrofuran; n-heptane;	5-(4-Ethoxycarbonyl-4-phenylpentyloxy)-2-methyl-2-phenylpentanoic acid ethyl ester (107). Under N2-atmosphere, to a stirred solution of 2-phenylpropionic acid ethyl ester (Dasseux, J.-L. H. et al. US 20030078239, 2003; U.S. patent application Ser. No. 09/976,938, filed Oct. 11, 2001) (13.2 g, 74.1 mmol) in anhydrous THF (50 mL) was added dropwise a solution of lithium diisopropylamide (39 mL, 78.0 mmol, 2.0 M in heptane/THF/ethylbenzene) at -78 C. After 1 h, DMPU (3 mL) was added, followed by the dropwise addition of a solution of 104 (9.2 g, 35.4 mmol) in THF (20 mL). After 30 min at -78 C., the reaction mixture was warmed to room temperature and stirred overnight. The reaction mixture was poured into a mixture of ice (30 g) and concd HCl (20 mL) and the product was extracted with diethyl ether (4*75 mL). The combined ether solutions were washed with 5% NaHCO3 solution (50 mL), and brine (50 mL), dried over MgSO4, and concentrated in vacuo to furnish the crude product (18.9 g) as a brown oil. Purification by column chromatography (silica; hexanes/ethyl acetate=10/1) gave 7 (4.3 g, 27%) as a yellow oil. 1H NMR (CDCl3): δ 7.45-7.10 (m, 10H), 4.11 (q, 4H, J=7.2), 3.45-3.25 (m, 4H), 2.15-1.85 (m, 4H), 1.54 (s, 6H), 1.50-1.35 (m, 4H), 1.17 (t, 6H, J=7.2). 13C NMR (CDCl3=77.00 ppm): δ 176.00, 143.71, 128.23, 126.50, 125.90, 70.89, 60.66, 49.86, 35.66, 25.08, 22.66, 14.02. HRMS (LSIMS, nba): Calcd for C28H39O5 (MH+): 455.2797, found: 455.2796.

References: [1]Journal of Medicinal Chemistry,2004,vol. 47,p. 5183 - 5197.
[2]Patent: WO2005/68410,2005,A1 .Location in patent: Page/Page column 232; 241.
[3]Patent: US2004/192771,2004,A1 .

26
[ 58929-72-9 ]
[ 171510-91-1 ]

References: [1]Journal of Medicinal Chemistry,2004,vol. 47,p. 5183 - 5197.
[2]Liebigs Annalen,1995,p. 1655 - 1662.

27
[ 58929-72-9 ]
5-(5-hydroxy-4-methyl-4-phenylpentyloxy)-2-methyl-2-phenylpentan-1-ol [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2004,vol. 47,p. 5183 - 5197.

28
[ 58929-72-9 ]
[ 171510-92-2 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

29
[ 58929-72-9 ]
[ 171511-04-9 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

30
[ 58929-72-9 ]
[ 171511-06-1 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

31
[ 58929-72-9 ]
[ 171511-00-5 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

32
[ 58929-72-9 ]
[ 171510-98-8 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

33
[ 58929-72-9 ]
5-((E)-4,4-Dimethyl-6-nitro-hex-5-enyloxy)-2,2-dimethyl-pentanal [ No CAS ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

34
[ 58929-72-9 ]
[ 171511-02-7 ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

35
[ 58929-72-9 ]
5,5,10,10-Tetramethyl-8-oxo-7-trimethylsiloxy-1-oxacyclotridecene [ No CAS ]

References: [1]Liebigs Annalen,1995,p. 1655 - 1662.

Historical Records

Technical Information

• Alkyl Halide Occurrence • General Reactivity • Grignard Reaction • Hiyama Cross-Coupling Reaction • Kinetics of Alkyl Halides • Kumada Cross-Coupling Reaction • Nomenclature of Ethers • Preparation of Ethers • Reactions of Alkyl Halides with Reducing Metals • Reactions of Amines • Reactions of Dihalides • Reactions of Ethers • Stille Coupling • Substitution and Elimination Reactions of Alkyl Halides • Suzuki Coupling

Related Functional Groups of
[ 58929-72-9 ]

Bromides

A182492 [36865-41-5]

1-Bromo-3-methoxypropane

Similarity: 0.93

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

{[proInfo.proName]}

CAS No.: 58929-72-9

{[proInfo.proName]}