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Chemical Structure| 5723-93-3 Chemical Structure| 5723-93-3

Structure of 5723-93-3

Chemical Structure| 5723-93-3

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Product Citations

Product Citations

Guo, Sheng ; Wu, Yifan ; Luo, Shao-Xiong Lennon ; Swager, Timothy M. ;

Abstract: Heterogenous catalysts with confined nanoporous catalytic sites are shown to have high activity and size selectivity. A solution-processable nanoporous organic polymer (1-BPy-Pd) catalyst displays high catalytic performance (TON > 200K) in the heterogeneous Suzuki–Miyaura coupling (SMC) reaction and can be used for the preparation of the intermediates in the synthesis of pharmaceutical agents. In comparison to the homogeneous catalyst analogue (2,2′-BPy)PdCl2, the heterogenous system offers size-dependent catalytic activity when bulkier substrates are used. Furthermore, the catalyst can be used to create catalytic impellers that simplify its use and recovery. We found that this system also works for applications in heterogenous Heck and nitroarenes reduction reactions. The metal-binding nanoporous polymer reported here represents a versatile platform for size-selective heterogeneous and recyclable catalysts.

Keywords: nanoporous organic polymer ; heterogeneous catalyst ; Suzuki−Miyaura coupling reaction ; size-selective reaction ; catalyst processing

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Product Details of [ 5723-93-3 ]

CAS No. :5723-93-3
Formula : C20H26
M.W : 266.42
SMILES Code : CC(C1=CC(C(C)(C)C)=CC(C2=CC=CC=C2)=C1)(C)C

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Application In Synthesis of [ 5723-93-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 5723-93-3 ]

[ 5723-93-3 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 92-52-4 ]
  • [ 507-20-0 ]
  • [ 1625-91-8 ]
  • [ 53692-25-4 ]
  • [ 53692-24-3 ]
  • [ 5723-93-3 ]
  • [ 343832-36-0 ]
  • [ 76783-53-4 ]
  • 2
  • [ 108-86-1 ]
  • [ 197223-39-5 ]
  • [ 5723-93-3 ]
YieldReaction ConditionsOperation in experiment
82% With potassium carbonate; In water; at 70℃; for 0.5h;Inert atmosphere; General procedure: In a typical run, h-BN(at)Fur(at)Pd(OAc)2 (0.05 mmol) was added to a mixture of arylboronic acid 1 (1.0 mmol), aryl bromide 2 (1.5 mmol) and K2CO3 (1.5 mmol) in water (1 mL). The resulting mixture was stirred at 70 °C under Ar protection, and the progress of the reaction was monitored by TLC. After completion of the reaction, ethyl acetate was added to the reaction mixture and the catalyst was separated. The organic phase was washed with water, dried over anhydrous Na2SO4 and the solvent was evaporated under reduced pressure. Finally, the residue was isolated by chromatography on a column of silica gel to afford the corresponding product 3.
 

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