Home Cart Sign in  
Chemical Structure| 556107-64-3 Chemical Structure| 556107-64-3

Structure of 556107-64-3

Chemical Structure| 556107-64-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 556107-64-3 ]

CAS No. :556107-64-3
Formula : C11H6BrN
M.W : 232.08
SMILES Code : N#CC1=CC=C2C(Br)=CC=CC2=C1
MDL No. :MFCD17012556
InChI Key :SSGFUDSHRVEIIF-UHFFFAOYSA-N
Pubchem ID :53485699

Safety of [ 556107-64-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P201-P202-P261-P264-P270-P271-P280-P302+P352-P304+P340-P308+P313-P310-P330-P361-P403+P233-P405-P501

Application In Synthesis of [ 556107-64-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 556107-64-3 ]

[ 556107-64-3 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 556107-64-3 ]
  • [ 1013-83-8 ]
  • 2
  • [ 1013-83-8 ]
  • [ 124-63-0 ]
  • [ 556107-64-3 ]
YieldReaction ConditionsOperation in experiment
With ammonia; In pyridine; hexane; chloroform; a) 5-Bromo-2-naphthonitrile To a solution of <strong>[1013-83-8]5-bromo-2-naphthoic acid</strong> (4.3 g, 17 mmol)) in dry pyridine (75 mL) at 0° C. was added methanesulfonyl chloride (1.4 mL, 18 mmol). After stirring at 0° C. for 1 h, ammonia gas was bubbled through the solution for 10 min, whilst maintaining the temperature below 5° C. During the gas addition the solution became viscous, so additional dry pyridine (~30 mL) was added. Excess ammonia was removed in vacuo, the solution again cooled to 0° C., then treated with additional methanesulfonyl chloride (12.5 mL) and allowed to warm to room temperature overnight. The solution was poured onto ice cold water, the mixture stirred for 30 min and the brown precipitate collected by filtration, washed on the sinter with ice cold water, then dried in vacuo. The crude product was dissolved in hot chloroform (~35 mL) and insoluble material filtered off. The chloroform was removed and the residue dissolved in a minimum volume of ether at reflux. Hexane was added until the solution remained turbid at reflux, the solution filtered rapidly into a pre-heated flask, and allowed to cool slowly to room temperature. The precipitate was collected by filtration, washed with hexane, and dried in vacuo, to yield 5-bromo-2-naphthonitrile. Further crops were obtained by cooling the filtrate at -18° C. overnight.
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 556107-64-3 ]

Aryls

Chemical Structure| 129278-20-2

A316512 [129278-20-2]

5-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 92616-49-4

A663481 [92616-49-4]

4-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 91065-17-7

A407657 [91065-17-7]

6-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 885227-79-2

A728337 [885227-79-2]

7-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 139914-16-2

A601873 [139914-16-2]

6,7-Dibromo-2-naphthonitrile

Similarity: 0.89

Bromides

Chemical Structure| 129278-20-2

A316512 [129278-20-2]

5-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 92616-49-4

A663481 [92616-49-4]

4-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 91065-17-7

A407657 [91065-17-7]

6-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 885227-79-2

A728337 [885227-79-2]

7-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 139914-16-2

A601873 [139914-16-2]

6,7-Dibromo-2-naphthonitrile

Similarity: 0.89

Nitriles

Chemical Structure| 129278-20-2

A316512 [129278-20-2]

5-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 92616-49-4

A663481 [92616-49-4]

4-Bromo-1-naphthonitrile

Similarity: 0.96

Chemical Structure| 91065-17-7

A407657 [91065-17-7]

6-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 885227-79-2

A728337 [885227-79-2]

7-Bromo-2-naphthonitrile

Similarity: 0.96

Chemical Structure| 139914-16-2

A601873 [139914-16-2]

6,7-Dibromo-2-naphthonitrile

Similarity: 0.89