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Chemical Structure| 55124-35-1 Chemical Structure| 55124-35-1

Structure of 55124-35-1

Chemical Structure| 55124-35-1

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Product Details of [ 55124-35-1 ]

CAS No. :55124-35-1
Formula : C6H18BN
M.W : 115.02
SMILES Code : [BH3-][NH+](C(C)C)C(C)C
MDL No. :MFCD01941198

Safety of [ 55124-35-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H227-H315-H319
Precautionary Statements:P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P403+P235-P501

Application In Synthesis of [ 55124-35-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 55124-35-1 ]

[ 55124-35-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 67-56-1 ]
  • [ 55124-35-1 ]
  • [ 17715-69-4 ]
  • [ 133730-34-4 ]
YieldReaction ConditionsOperation in experiment
70% General procedure: To a solution in THF (4 mL) of DIPAB (863 mg, 7.5 mmol) and Mg (182 mg, 7.5 mmol) were added a PhMgBr 1M THF solution (375 μL, 375μmol) at room temperature. After 10 min, 30 mL of anhydrous THF were added followed by the arylbromide (5 mmol). The reaction mixture was cooled down to 0 C and quenched slowly with 7 mL of MeOH. After 1h, volatile were removed under reduced pressure and the resulting solid was dissolved in 1N HCl/MeOH (7/3). After 1h at room temperature, 100 mL of AcOEt were added, the organic phase was washed with 1N HCl (30 mL) and brine (3×30 mL). Organic phases were concentrated under reduced pressure yielding a solid which was recrystallized from H2O.
 

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