Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 542-58-5 Chemical Structure| 542-58-5

Structure of 2-Chloroethyl Acetate
CAS No.: 542-58-5

Chemical Structure| 542-58-5

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 542-58-5 ]

CAS No. :542-58-5
Formula : C4H7ClO2
M.W : 122.55
SMILES Code : CC(OCCCl)=O
MDL No. :MFCD00018963
InChI Key :VIRWKAJWTKAIMA-UHFFFAOYSA-N
Pubchem ID :10959

Safety of [ 542-58-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H226-H300
Precautionary Statements:P210-P233-P240-P241+P242+P243-P264-P270-P280-P301+P310+P330-P303+P361+P353-P403+P235-P405-P501
Class:6.1(3)
UN#:2929
Packing Group:

Application In Synthesis of [ 542-58-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 542-58-5 ]
  • Downstream synthetic route of [ 542-58-5 ]

[ 542-58-5 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 35320-23-1 ]
  • [ 542-58-5 ]
  • [ 119844-67-6 ]
YieldReaction ConditionsOperation in experiment
26%
Stage #1: With sodium hydride In tetrahydrofuran at 20℃; for 0.583333 h;
Stage #2: at 20℃; for 18 h; Heating / reflux
1) (5R)-5-Methyl-3-morpholinone Sodium hydride (55percent, 0.820 g) was added to a solution of (2R)-2-amino-1-propanol (1.33 mL) in tetrahydrofuran (200 mL) at room temperature, and the resultant mixture was stirred for 35 minutes. Chloroethyl acetate (1.80 mL) was added to the reaction solution over 5 minutes at room temperature, and the mixture was stirred for 25 minutes, and then heated to reflux for 17.5 hours. After air cooling, the reaction solution was filtered, and a residue obtained by evaporating the solvent of the filtrate under reduced pressure was purified by silica gel column chromatography (ethyl acetate-n-hexane), to obtain a crude product of (5R)-5-methyl-3-morpholinone (0.520 g, 26percent) as an oily product.
References: [1] Patent: EP1785418, 2007, A1, . Location in patent: Page/Page column 149.
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 542-58-5 ]

Aliphatic Chain Hydrocarbons

Chemical Structure| 17229-14-0

A149345 [17229-14-0]

Ethyl 2-(2-chloroethoxy)acetate

Similarity: 0.83

Chlorides

Chemical Structure| 17229-14-0

A149345 [17229-14-0]

Ethyl 2-(2-chloroethoxy)acetate

Similarity: 0.83

Esters

Chemical Structure| 17229-14-0

A149345 [17229-14-0]

Ethyl 2-(2-chloroethoxy)acetate

Similarity: 0.83