Home Cart Sign in  
Chemical Structure| 50487-71-3 Chemical Structure| 50487-71-3

Structure of 50487-71-3

Chemical Structure| 50487-71-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Product Citations

Qiao Lin ; Ethan H. Spielvogel ; Tianning Diao ;

Abstract: The capture of carbon-centered radicals at a nickel(II) center is commonly featured in recent cross-coupling and metallaphotoredox catalytic reactions. Despite its widespread application in catalysis, this fundamental step lacks experimental characterization. This report portrays radical capture at catalytically relevant nickel(II) centers from several aspects, including the structure-activity relationships of the ligands, the mechanism, the kinetics, and the stereoselectivity. Spectroscopic data provide evidence for the formation of a nickel(III) intermediate. Strikingly different reactivity between nickel-aryl and nickel-alkyl complexes implies different rate-determining steps for C(sp3)–C(sp3) and C(sp2)–C(sp3) bond formation. Kinetic data benchmark the capture rates on the scale of 10[7] M−1s−1 and 10[6] M−1s−1 for primary and secondary radicals, respectively. Overall, the activation energy is higher than that of previous computational estimations. Finally, stoichiometric experiments with well-defined chiral nickel complexes demonstrate that the radical trapping step can confer diastereoselectivity and enantioselectivity with a drastic ligand effect.

Alternative Products

Product Details of [ 50487-71-3 ]

CAS No. :50487-71-3
Formula : C10H13NO2S
M.W : 211.28
SMILES Code : CC1=CC=C(S(=O)(NCC=C)=O)C=C1
MDL No. :MFCD00182633
InChI Key :SQMCYQSCMCMEIL-UHFFFAOYSA-N
Pubchem ID :297877

Safety of [ 50487-71-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 50487-71-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 50487-71-3 ]
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 50487-71-3 ]

Aryls

Chemical Structure| 180720-24-5

A683061 [180720-24-5]

(E)-4-Methyl-N-(pent-2-en-1-yl)benzenesulfonamide

Similarity: 0.95

Chemical Structure| 402925-22-8

A132689 [402925-22-8]

4-(Aminomethyl)-N-ethylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 80-39-7

A690478 [80-39-7]

N-Ethyl-4-methylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 78388-18-8

A588110 [78388-18-8]

N-(But-3-en-2-yl)-4-methylbenzenesulfonamide

Similarity: 0.91

Chemical Structure| 837-18-3

A785045 [837-18-3]

N-Benzylbenzenesulfonamide

Similarity: 0.91

Alkenyls

Chemical Structure| 180720-24-5

A683061 [180720-24-5]

(E)-4-Methyl-N-(pent-2-en-1-yl)benzenesulfonamide

Similarity: 0.95

Chemical Structure| 78388-18-8

A588110 [78388-18-8]

N-(But-3-en-2-yl)-4-methylbenzenesulfonamide

Similarity: 0.91

Amines

Chemical Structure| 180720-24-5

A683061 [180720-24-5]

(E)-4-Methyl-N-(pent-2-en-1-yl)benzenesulfonamide

Similarity: 0.95

Chemical Structure| 402925-22-8

A132689 [402925-22-8]

4-(Aminomethyl)-N-ethylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 80-39-7

A690478 [80-39-7]

N-Ethyl-4-methylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 78388-18-8

A588110 [78388-18-8]

N-(But-3-en-2-yl)-4-methylbenzenesulfonamide

Similarity: 0.91

Chemical Structure| 837-18-3

A785045 [837-18-3]

N-Benzylbenzenesulfonamide

Similarity: 0.91

Sulfamides

Chemical Structure| 180720-24-5

A683061 [180720-24-5]

(E)-4-Methyl-N-(pent-2-en-1-yl)benzenesulfonamide

Similarity: 0.95

Chemical Structure| 402925-22-8

A132689 [402925-22-8]

4-(Aminomethyl)-N-ethylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 80-39-7

A690478 [80-39-7]

N-Ethyl-4-methylbenzenesulfonamide

Similarity: 0.92

Chemical Structure| 78388-18-8

A588110 [78388-18-8]

N-(But-3-en-2-yl)-4-methylbenzenesulfonamide

Similarity: 0.91

Chemical Structure| 837-18-3

A785045 [837-18-3]

N-Benzylbenzenesulfonamide

Similarity: 0.91