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Chemical Structure| 46471-67-4 Chemical Structure| 46471-67-4

Structure of 46471-67-4

Chemical Structure| 46471-67-4

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Product Details of [ 46471-67-4 ]

CAS No. :46471-67-4
Formula : C11H18O4S
M.W : 246.32
SMILES Code : O=S(CC1(C2(C)C)C(CC2CC1)=O)(OC)=O
MDL No. :MFCD30180397
InChI Key :PIZJIRRXGXBJAU-UHFFFAOYSA-N
Pubchem ID :573022

Safety of [ 46471-67-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 46471-67-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 46471-67-4 ]

[ 46471-67-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 136310-64-0 ]
  • [ 46471-67-4 ]
  • C10H15O4S(1-)*C19H22NO4S2(1+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
80% In dichloromethane; acetonitrile; at 20℃; for 24h; 9-Methyl-3-oxa-9-azatricyclo[3.3.1.02'4]non-7-yl hydroxy(di-2-thienyl) acetate (0.1 mol) was suspended in a mixture of methylene chloride/ acetonitrile (76 ml: 115 ml; 1 :1.5 v/v). To the mixture methyl (+/-)-IO-camphorsulphonate (0.5 mol) in 73 ml of acetonitrile was added. Reaction was carried out for 24h at room temperature. Then the reaction mixture was concentrated by evaporation until crystals precipitated and the obtained crystals were triturated in acetone, filtered off and dried in vacuum dryer at 3O0C. Yield: 80%, HPLC purity: 99.70%.
 

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