[ CAS No. 448-59-9 ] {[proInfo.proName]}

Name: 448-59-9|2,4,6-Tris(4-fluorophenyl)-1,3,5,2,4,6-trioxatriborinane|98%
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COA NMR CNMR HPLC LC-MS

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CAS No. :	448-59-9	MDL No. :	MFCD02093496
Formula :	C₁₈H₁₂B₃F₃O₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	AHYNJLHYJZXUSD-UHFFFAOYSA-N
M.W :	365.71	Pubchem ID :	2769359
Synonyms :

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Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 448-59-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 448-59-9 ]
Downstream synthetic route of [ 448-59-9 ]

[ 448-59-9 ] Synthesis Path-Upstream 1~1

1
[ 76-09-5 ]
[ 448-59-9 ]
[ 214360-58-4 ]

Reference： [1] Journal of the American Chemical Society, 2011, vol. 133, # 7, p. 2116 - 2119

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Yield	Reaction Conditions	Operation in experiment
99%	Stage #1: 4-fluoroboronic acid In chloroform; ethyl acetate at 20℃; for 0.5h; Stage #2: With magnesium(II) sulfate In chloroform; ethyl acetate for 3h;
89%	In toluene for 24h; Reflux; Dean-Stark; Inert atmosphere;
40%	In toluene byproducts: H2O; azeotropic treatment; crystn. from toluene, storage over P4O10, elem. anal.;

	In benzene Heating;
	In neat (no solvent) thermal dehydration at 100-300 °C;
	In toluene Reflux; Inert atmosphere;
	In benzene for 2h; Inert atmosphere; Reflux;
	In toluene Reflux;
	Reflux;
	at 110 - 130℃; Inert atmosphere;
	In toluene for 6h; Azeotropic distillation;
	In toluene for 6h; Azeotropic distillation conditions;
	Heating; vacuum;
	In water monomer Heating;
	at 110 - 130℃; Inert atmosphere;
	at 125℃;
	In toluene Dean-Stark;
	In toluene at 140℃; for 3h; Dean-Stark;
	at 120℃; for 48h;
	In toluene for 3h; Reflux;
	In toluene for 2h; Reflux; Dean-Stark;
	at 120℃;
	In toluene Dean-Stark; Inert atmosphere;
	In toluene Dean-Stark;
	In toluene for 2h; Reflux; Dean-Stark;
	In toluene for 2h; Reflux; Inert atmosphere; Dean-Stark;
	at 160℃; for 16h; Inert atmosphere;
	In toluene for 24h; Reflux; Dean-Stark; Inert atmosphere;

Yield	Reaction Conditions	Operation in experiment
	With 1,2-bis((2R,5R)-2,5-diethylphosphoranylidene)benzene; sodium t-butanolate In 1,2-dimethoxyethane; water at 100℃; for 48h; Title compound not separated from byproducts.;
	With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; 1,2-bis((2R,5R)-2,5-diethylphosphoranylidene)benzene; sodium t-butanolate In 1,2-dimethoxyethane; water at 100℃; for 48h; optical yield given as %ee; enantioselective reaction;

Yield	Reaction Conditions	Operation in experiment
71%	With water; potassium hydroxide In tetrahydrofuran for 0.333333h; Sonication; Inert atmosphere;
	Multi-step reaction with 2 steps 1: water / acetone / Inert atmosphere 2: water; potassium carbonate / tetrahydrofuran / 20 °C / Inert atmosphere

[ CAS No. 448-59-9 ] {[proInfo.proName]}

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