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Chemical Structure| 405165-14-2 Chemical Structure| 405165-14-2

Structure of 405165-14-2

Chemical Structure| 405165-14-2

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Product Details of [ 405165-14-2 ]

CAS No. :405165-14-2
Formula : C18H31BO2S
M.W : 322.31
SMILES Code : CC1(C)C(C)(C)OB(C2=C(CCCCCCCC)C=CS2)O1
MDL No. :MFCD27976834
InChI Key :QGVDWQHOZUDLGM-UHFFFAOYSA-N
Pubchem ID :59718130

Safety of [ 405165-14-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 405165-14-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 405165-14-2 ]

[ 405165-14-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4805-22-5 ]
  • [ 405165-14-2 ]
  • [ 153938-82-0 ]
YieldReaction ConditionsOperation in experiment
4.53 g With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate; In N,N-dimethyl-formamide; at 100℃; for 4h; The compound (1-h)4. 53g dissolved in tetrahydrofuran (wako pure chemical industries (strain) made) 40 ml in, -80 C in cooling. N -1. 6M Phenylbicyclohexane soln. (wako pure chemical industries (strain) made) 6. 1 ml is added, is heated up to 5 C-, -80 C in cooling. 2-isopropoxydiphenyl -4, 4, 5, 5-tetramethyl -1, 3, 2-dioxaborolane (wako pure chemical industries (strain) made) 2. 3 ml is added, and heated to room temperature, the stirring 2 hours in a nitrogen atmosphere. A solution obtained by adding 150 ml and ethyl acetate 200 ml 1N aqueous ammonium chloride, fractionating the organic layer, after washing with 200 ml water, dried with magnesium sulfate. The resultant solution to column chromatography (filler: silica gel, eluent: dichlomethane/Phenylbicyclohexane) is purified by, compd. (1-i)2. 31g is obtained.
 

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