There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
*Storage: {[sel_prStorage]}
*Shipping: {[sel_prShipping]}
The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
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Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 2456-81-7 |
Formula : | C9H12N2 |
M.W : | 148.21 |
SMILES Code : | C1(N2CCCC2)=CC=NC=C1 |
MDL No. : | MFCD00006415 |
InChI Key : | RGUKYNXWOWSRET-UHFFFAOYSA-N |
Pubchem ID : | 75567 |
GHS Pictogram: |
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Signal Word: | Danger |
Hazard Statements: | H301-H314 |
Precautionary Statements: | P280-P305+P351+P338-P310-P304+P340-P301+P330+P331-P303+P361+P353 |
Class: | 8(6.1) |
UN#: | 2923 |
Packing Group: | Ⅲ |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
96% | With water-d2; at 190℃; for 2h;Microwave irradiation; | General procedure: A solution of the substrate in D2O (5 mL) was irradiated in a sealed Pyrex tube at 190 °C for 2 h (hold-time) using a CEM Explorer microwave synthesizer (maximum pressure 150 psi) by moderation of the initial microwave power (300 W). The mixture was cooled in a stream of compressed air and extracted with CH2Cl2 (3 × 10 mL). The organic extracts were combined, dried (MgSO4), filtered and evaporated in vacuo to give the title compound. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
66% | EXAMPLE 7 4-pyrrolidinopyridine To a 250 ml, 3-neck round bottom flask equipped with a thermometer, pressure equalizing addition funnel and magnetic stir bar, was charged 10.6 ml of pyrrolidine (0.125 mole) and 13.5 ml of deionized water. The flask was cooled in an ice water bath and 10 g (0.125 mole) of a 50percent (w/w) sodium hydroxide solution was added slowly with stirring. Upon complete addition, the solution was cooled below 5° C. A solution of 1-(2-carbamoylethyl)-4-cyanopyridinium chloride (21.2 g; 0.1 mole) dissolved in 15 ml of deionized water was prepared and charged to the dropping funnel. This solution was then added to the pyrrolidine/sodium hydroxide solution at a rate which permitted maintenance of the reaction temperature with stirring at below 5° C. It was held there for an additional hour, after which 14 g (0.175 mole) of a 50percent (w/w) sodium hydroxide solution was added dropwise with continued maintenance of the reaction temperature below 5° C. (approximately 45 minutes). The mixture was then heated to reflux and maintained for two hours and then allowed to cool. The aqueous mixture was extracted four times with half its volume of toluene and the combined extracts were concentrated to a residue of 14.7 g which solidified. This crude material was crystallized from ethylacetate to give 4.04 g of the title compound as product, mp. 58°-59° C. (66percent yield). |