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Chemical Structure| 37859-25-9 Chemical Structure| 37859-25-9

Structure of 37859-25-9

Chemical Structure| 37859-25-9

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Product Details of [ 37859-25-9 ]

CAS No. :37859-25-9
Formula : C12H9ClO
M.W : 204.65
SMILES Code : O=C(Cl)CC1=CC=C2C=CC=CC2=C1
MDL No. :MFCD02180524
InChI Key :QEJGMKHQXSZCOS-UHFFFAOYSA-N
Pubchem ID :588115

Safety of [ 37859-25-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 37859-25-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 37859-25-9 ]

[ 37859-25-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 37859-25-9 ]
  • [ 3846-71-7 ]
  • 2-[2-(1-naphthylacetoxy)-3,5-di(tert-butyl)-phenyl]-benzotriazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine; In dichloromethane; Example C - Esterification with acid chloride 0.12 mol of triethylamine is added to a solution of 0.08 mol of 2-[2-hydroxy-3,5-di(tert-butyl)-phenyl]-benzotriazole in 150 ml of methylene chloride. To this solution is slowly added dropwise at 10°-15° C., with stirring, a solution of 0.08 mol of 2-naphthylacetyl chloride in 50 ml of methylene chloride. The temperature is then allowed to rise to 20°-25° C., and the mixture is stirred for 6 hours at this temperature. The triethylammonium chloride which has precipitated is filtered off, and the filtrate is washed with water, dried over Na2 SO4 and concentrated by evaporation. The crystalline, reddish-coloured residue is recrystallized from hexane to thus obtain 2-[2-(1-naphthylacetoxy)-3,5-di(tert-butyl)-phenyl]-benzotriazole in the form of white crystals which melt at 150°-151° C. (compound No. 25). There are obtained in an analogous manner the following phenol esters of the general formula STR8
 

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