36997-31-6|Benzene-1,3,5-tricarboxylic acid trihydrazide| Ambeed

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Quality Control of [ 36997-31-6 ] Purity: 95% SDS Specification

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Product Details of [ 36997-31-6 ]

CAS No. :	36997-31-6
Formula :	C₉H₁₂N₆O₃
M.W :	252.23
SMILES Code :	NNC(C1=CC(C(NN)=O)=CC(C(NN)=O)=C1)=O
MDL No. :	MFCD16172194
InChI Key :	MNBHRGAIQJFCIO-UHFFFAOYSA-N
Pubchem ID :	15320491

Safety of [ 36997-31-6 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H315-H319
Precautionary Statements:	P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Application In Synthesis of [ 36997-31-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 36997-31-6 ]

[ 36997-31-6 ] Synthesis Path-Downstream 1~35

1
[ 4105-92-4 ]
[ 36997-31-6 ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1915,vol. <2> 91,p. 67.
[2]Synthetic Communications,2007,vol. 37,p. 1457 - 1462.

2
[ 4422-95-1 ]
[ 36997-31-6 ]

References: [1]Chemische Berichte,1959,vol. 92,p. 2532,2538.
[2]Synthetic Communications,2007,vol. 37,p. 1457 - 1462.

3
[ 36997-31-6 ]
[ 100-52-7 ]
benzene-1,3,5-tricarboxylic acid tris-benzylidenehydrazide [ No CAS ]

References: [1]Journal fur praktische Chemie (Leipzig 1954),1915,vol. <2> 91,p. 67.

4
[ 36997-31-6 ]
[ 98-09-9 ]
[ 117882-60-7 ]

References: [1]Chemische Berichte,1959,vol. 92,p. 2532,2538.

5
[ 36997-31-6 ]
[ 123-54-6 ]
[ 118927-16-5 ]

References: [1]Chemische Berichte,1959,vol. 92,p. 2532,2538.

6
[ 201230-82-2 ]
[ 36997-31-6 ]
[ 175791-96-5 ]
[ 175791-97-6 ]
3,5-Bis-[5-(4-tert-butyl-phenyl)-[1,3,4]oxadiazol-2-yl]-benzoate2,3,4,6,7,8,9,10-octahydro-1H-pyrimido[1,2-a]azepin-5-ylium; [ No CAS ]

References: [1]Journal of the Chemical Society. Chemical communications,1996,p. 77 - 80.

7
[ 36997-31-6 ]
Trifluoro-methanesulfonate[(2E,4Z)-5-ethoxy-1,5-di-p-tolyl-penta-2,4-dien-(Z)-ylidene]-ethyl-oxonium; [ No CAS ]
C₆₆H₅₇N₆O₃⁽³⁺⁾*3CF₃O₃S^(1-) [ No CAS ]

References: [1]Tetrahedron Letters,1998,vol. 39,p. 4809 - 4812.

8
[ 36997-31-6 ]
Trifluoro-methanesulfonate[(2E,4Z)-5-ethoxy-1,5-di-p-tolyl-penta-2,4-dien-(Z)-ylidene]-ethyl-oxonium; [ No CAS ]
C₇₂H₇₂N₆O₆*3CHF₃O₃S [ No CAS ]

References: [1]Tetrahedron Letters,1998,vol. 39,p. 4809 - 4812.

10
[ 36997-31-6 ]
[ 347165-20-2 ]

References: [1]Synthetic Communications,2007,vol. 37,p. 1457 - 1462.

11
[ 554-95-0 ]
[ 36997-31-6 ]

References: [1]Synthetic Communications,2007,vol. 37,p. 1457 - 1462.
[2]Chemische Berichte,1959,vol. 92,p. 2532,2538.

12
[ 1121-60-4 ]
[ 36997-31-6 ]
C₂₇H₂₁N₉O₃ [ No CAS ]

References: [1]Angewandte Chemie - International Edition,2008,vol. 47,p. 877 - 881.

13
[ 5470-96-2 ]
[ 36997-31-6 ]
C₃₉H₂₇N₉O₃ [ No CAS ]

References: [1]Angewandte Chemie - International Edition,2008,vol. 47,p. 877 - 881.

14
[ 2672-58-4 ]
[ 36997-31-6 ]

Yield	Reaction Conditions	Operation in experiment
81.2%	With hydrazine hydrate; In ethanol; at 80.0℃; for 24.0h;	In a 250mL round-bottomed flask, 100ml of ethanol and 1,3,5-tricarboxylic acid tricresyl ester (1.39g, 5mmol) were added, and then 8ml of hydrazine hydrate was added dropwise, and the reaction was stirred and refluxed at 80C for 24h. After the completion of the reaction, the reaction solution was cooled to room temperature, and a large amount of solid was precipitated and filtered under reduced pressure. The filter cake was washed 3 times with ethanol and dried to obtain pure target compound (3) (1,2,3,5-trihydrazide). Yield 81.2%,
	With hydrazine hydrate; In ethanol; for 8.0h;Reflux;	Synthesis of intermediate product: Weighing Trimethyl benzenetricarboxylate (5.0 g, 0.02 mol), hydrazine hydrate (85%, 3.79 g, 0.065 mol), Add to a 250 mL flask containing 150 mL of ethanol, reflux under magnetic stirring for 8 h, and disperse heat into a beaker containing a large amount of water. Filtration and recrystallization from ethanol, drying to obtain an intermediate product, to be used; Synthesis of Al3+ probe compounds: The intermediate product (5.0 g, 0.02 mol), salicylaldehyde (7.3 g, 0.06 mol) was weighed and added to a 250 mL flask containing 100 mL of DMF.The reaction was stirred magnetically at 90 C for 8 h, and the heat was dispersed into a beaker containing a large amount of water. Filtered and washed three times with ethanol at 0.06 MPa, Drying under vacuum at 60 C gave a white powdery pure Al3+ probe compound. The calculated yield was 96%.
	With ethanol; hydrazine hydrate; at 20.0℃; for 8.0h;	(1) The trimesic acidTrimethyl ester (5.0g, 0.02mol) and hydrazine hydrate (85%, 3.79g, 0.065mol) were added to a 250mL flask containing 150mL of ethanol, refluxed for 8h under magnetic stirring at room temperature, and dispersed until it was heated to a large amount of water In the beaker, suction filtered and recrystallized with ethanol,After drying, the product trimesic hydrazide is obtained;

References: [1]Journal of Physical Chemistry B,2010,vol. 114,p. 756 - 768.
[2]New Journal of Chemistry,2021,vol. 45,p. 18764 - 18768.
[3]Angewandte Chemie - International Edition,2008,vol. 47,p. 877 - 881.
[4]Patent: CN112125823,2020,A .Location in patent: Paragraph 0031-0032.
[5]Chemical Communications,2018,vol. 54,p. 13674 - 13677.
[6]New Journal of Chemistry,2021,vol. 45,p. 1899 - 1903.
[7]Chemical Communications,2020,vol. 56,p. 13638 - 13641.
[8]RSC Advances,2017,vol. 7,p. 54407 - 54415.
[9]Patent: CN109503422,2019,A .Location in patent: Paragraph 0010; 0011; 0012; 0014.
[10]Angewandte Chemie - International Edition,2020,vol. 59,p. 4168 - 4175.
Angew. Chem.,2020,vol. 132,p. 4197 - 4204,8.
[11]Patent: CN111423339,2020,A .Location in patent: Paragraph 0017-0028.

15
[ 36997-31-6 ]
[ 98-88-4 ]
N',N''',N'''''-tri(benzoyl)benzene-1,3,5-tricarboxylic acid trihydrazide [ No CAS ]

References: [1]Journal of Physical Chemistry B,2010,vol. 114,p. 756 - 768.

16
[ 24677-78-9 ]
[ 36997-31-6 ]
[ 1380230-41-0 ]

Yield	Reaction Conditions	Operation in experiment
82%	In methanol; for 24.0h;Reflux;	General procedure: The ligands H6L1-7 were prepared by similar methods. A representativemethod for I is presented here. A solution of salicylaldehyde(1.46 g, 12 mmol) in MeOH (30 mL) was added to amethanolic suspension of <strong>[36997-31-6]benzene-1,3,5-tricarbohydrazide</strong>(0.504 g, 2 mmol). The reaction mixture was refluxed on an oilbath. During this period, the <strong>[36997-31-6]benzene-1,3,5-tricarbohydrazide</strong>slowly dissolved and simultaneously a white solid precipitated.After 24 h of reflux, the reaction mixture was cooled at room temperaturefor an hour, the precipitated solid was filtered, washedwith MeOH (2 5 mL) and dried in a desiccator over silica gel.Data for H6L1 (I): Yield 0.954 g (85%). Anal. Calc. for C30H24N6O6(5 6 4): C, 63.83; H, 4.29; N, 14.89. Found: C, 65.31; H, 4.82; N,13.83%. IR data (cm1): 3440 (OAH), 3018 (NAH), 1659 (CO),1563 (CN).

References: [1]Polyhedron,2020,vol. 186.
[2]European Journal of Organic Chemistry,2012,p. 2422 - 2427.

17
[ 367-57-7 ]
[ 36997-31-6 ]
C₂₄H₁₅F₉N₆O₃ [ No CAS ]

References: [1]Dalton Transactions,2013,vol. 42,p. 16878 - 16886.

18
[ 36997-31-6 ]
[ 1008-72-6 ]
C₃₀H₂₁N₆O₁₂S₃^(3-)*3Na⁽¹⁺⁾ [ No CAS ]

References: [1]Dalton Transactions,2015,vol. 44,p. 66 - 70.

19
[ 653-37-2 ]
[ 36997-31-6 ]
C₃₀H₉F₁₅N₆O₃ [ No CAS ]

References: [1]Chemical Communications,2018,vol. 54,p. 13674 - 13677.

20
[ 36997-31-6 ]
[ 90-02-8 ]
tris-(2-hydroxybenzylidene)benzene-1,3,5-tricarbohydrazide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
85%	In methanol; for 24.0h;Reflux;	The ligands H6L1-7 were prepared by similar methods. A representativemethod for I is presented here. A solution of salicylaldehyde(1.46 g, 12 mmol) in MeOH (30 mL) was added to amethanolic suspension of <strong>[36997-31-6]benzene-1,3,5-tricarbohydrazide</strong>(0.504 g, 2 mmol). The reaction mixture was refluxed on an oilbath. During this period, the <strong>[36997-31-6]benzene-1,3,5-tricarbohydrazide</strong>slowly dissolved and simultaneously a white solid precipitated.After 24 h of reflux, the reaction mixture was cooled at room temperaturefor an hour, the precipitated solid was filtered, washedwith MeOH (2 5 mL) and dried in a desiccator over silica gel.Data for H6L1 (I): Yield 0.954 g (85%). Anal. Calc. for C30H24N6O6(5 6 4): C, 63.83; H, 4.29; N, 14.89. Found: C, 65.31; H, 4.82; N,13.83%. IR data (cm1): 3440 (OAH), 3018 (NAH), 1659 (CO),1563 (CN).
	In N,N-dimethyl-formamide; at 90.0℃; for 8.0h;	Synthesis of intermediate product: Weighing Trimethyl benzenetricarboxylate (5.0 g, 0.02 mol), hydrazine hydrate (85%, 3.79 g, 0.065 mol), Add to a 250 mL flask containing 150 mL of ethanol, reflux under magnetic stirring for 8 h, and disperse heat into a beaker containing a large amount of water. Filtration and recrystallization from ethanol, drying to obtain an intermediate product, to be used; Synthesis of Al3+ probe compounds: The intermediate product (5.0 g, 0.02 mol), salicylaldehyde (7.3 g, 0.06 mol) was weighed and added to a 250 mL flask containing 100 mL of DMF. The reaction was stirred magnetically at 90 C for 8 h, and the heat was dispersed into a beaker containing a large amount of water. Filtered and washed three times with ethanol at 0.06 MPa, Drying under vacuum at 60 C gave a white powdery pure Al3+ probe compound. The calculated yield was 96%.

References: [1]New Journal of Chemistry,2019,vol. 43,p. 17557 - 17570.
[2]Polyhedron,2020,vol. 186.
[3]Patent: CN109503422,2019,A .Location in patent: Paragraph 0010; 0011; 0012; 0014.

21
trans-oxotribromobis(triphenylphosphine)rhenium(V) [ No CAS ]
[ 36997-31-6 ]
[ 67-64-1 ]
C₇₂H₆₆Br₆N₆O₆P₃Re₃ [ No CAS ]

References: [1]New Journal of Chemistry,2020,vol. 44,p. 7080 - 7090.

22
[ 37942-07-7 ]
[ 36997-31-6 ]
C₅₄H₇₂N₆O₆ [ No CAS ]