Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 345-35-7 Chemical Structure| 345-35-7

Structure of 345-35-7

Chemical Structure| 345-35-7

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 345-35-7 ]

CAS No. :345-35-7
Formula : C7H6ClF
M.W : 144.57
SMILES Code : FC1=CC=CC=C1CCl
MDL No. :MFCD00000892
InChI Key :MOBRMRJUKNQBMY-UHFFFAOYSA-N
Pubchem ID :9580

Safety of [ 345-35-7 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8(3)
UN#:2920
Packing Group:

Application In Synthesis of [ 345-35-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 345-35-7 ]
  • Downstream synthetic route of [ 345-35-7 ]

[ 345-35-7 ] Synthesis Path-Upstream   1~2

  • 1
  • [ 345-35-7 ]
  • [ 51859-98-4 ]
References: [1] Journal of Agricultural and Food Chemistry, 2012, vol. 60, # 44, p. 10942 - 10951.
  • 2
  • [ 345-35-7 ]
  • [ 73183-34-3 ]
  • [ 517920-60-4 ]
YieldReaction ConditionsOperation in experiment
82% With iron(III)-acetylacetonate; magnesium In tetrahydrofuran at 0℃; for 3 h; Inert atmosphere Example 7: In the condition of adding magnesium turnings in situ,The boron esterification of ortho-fluorobenzyl chloride and bis-boronic acid pinacol ester catalyzed by Fe(acac)3 was followed by the addition of the catalyst (3.5 mg, 0.010 mmol, 2 molpercent) under argon atmosphere.Bis(pinacolato)boronic acid ester (127.0 mg, 0.5 mmol),Magnesium turnings (16.8 mg, 0.7 mmol), tetrahydrofuran (1 mL),After addition of o-fluorobenzyl chloride (160 μl, 1.35 mmol) at 0°C,The reaction was carried out for 3 hours, and the reaction was terminated with the addition of water. The reaction product was extracted with ethyl acetate and the yield was 82percent as calculated by gas chromatography.
References: [1] Patent: CN107903281, 2018, A, . Location in patent: Paragraph 0030.
[2] Tetrahedron Letters, 2003, vol. 44, # 2, p. 233 - 235.
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 345-35-7 ]

Fluorinated Building Blocks

Chemical Structure| 452-07-3

A267968 [452-07-3]

1-(Chloromethyl)-2,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 697-73-4

A752620 [697-73-4]

2-(Chloromethyl)-1,3-difluorobenzene

Similarity: 0.97

Chemical Structure| 495-07-8

A145543 [495-07-8]

2-(Chloromethyl)-1,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 1214362-43-2

A513286 [1214362-43-2]

4-(Chloromethyl)-3,3'-difluoro-1,1'-biphenyl

Similarity: 0.90

Chemical Structure| 1214362-43-2

A513286 [1214362-43-2]

4-(Chloromethyl)-3,3'-difluoro-1,1'-biphenyl

Similarity: 0.90

Aryls

Chemical Structure| 452-07-3

A267968 [452-07-3]

1-(Chloromethyl)-2,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 697-73-4

A752620 [697-73-4]

2-(Chloromethyl)-1,3-difluorobenzene

Similarity: 0.97

Chemical Structure| 495-07-8

A145543 [495-07-8]

2-(Chloromethyl)-1,4-difluorobenzene

Similarity: 0.97

Chlorides

Chemical Structure| 452-07-3

A267968 [452-07-3]

1-(Chloromethyl)-2,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 697-73-4

A752620 [697-73-4]

2-(Chloromethyl)-1,3-difluorobenzene

Similarity: 0.97

Chemical Structure| 495-07-8

A145543 [495-07-8]

2-(Chloromethyl)-1,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 1214362-43-2

A513286 [1214362-43-2]

4-(Chloromethyl)-3,3'-difluoro-1,1'-biphenyl

Similarity: 0.90

Benzyl Chlorides

Chemical Structure| 452-07-3

A267968 [452-07-3]

1-(Chloromethyl)-2,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 697-73-4

A752620 [697-73-4]

2-(Chloromethyl)-1,3-difluorobenzene

Similarity: 0.97

Chemical Structure| 495-07-8

A145543 [495-07-8]

2-(Chloromethyl)-1,4-difluorobenzene

Similarity: 0.97

Chemical Structure| 1214362-43-2

A513286 [1214362-43-2]

4-(Chloromethyl)-3,3'-difluoro-1,1'-biphenyl

Similarity: 0.90

Chemical Structure| 1214362-43-2

A513286 [1214362-43-2]

4-(Chloromethyl)-3,3'-difluoro-1,1'-biphenyl

Similarity: 0.90