Home Cart Sign in  
Chemical Structure| 3383-21-9 Chemical Structure| 3383-21-9

Structure of 3383-21-9

Chemical Structure| 3383-21-9

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 3383-21-9 ]

CAS No. :3383-21-9
Formula : C14H20O2
M.W : 220.31
SMILES Code : O=C(C(C(C)(C)C)=CC(C(C)(C)C)=C1)C1=O
MDL No. :MFCD00001647
InChI Key :NOUZOVBGCDDMSX-UHFFFAOYSA-N
Pubchem ID :76915

Safety of [ 3383-21-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 3383-21-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3383-21-9 ]

[ 3383-21-9 ] Synthesis Path-Downstream   1~6

  • 1
  • [ 3383-21-9 ]
  • [ 262373-15-9 ]
  • 1,3-di-tert-butyl-6-methyl-1,4-dihydro-1,4-ethanonaphthalene-9,10-dione [ No CAS ]
  • 1,3-di-tert-butyl-7-methyl-1,4-dihydro-1,4-ethanonaphthalene-9,10-dione [ No CAS ]
  • 2
  • [ 558478-81-2 ]
  • [ 3383-21-9 ]
  • 5-cyclopropyl-1-(3,5-di-tert-butyl-2-hydroxyphenyl)pyrrolidin-2-one [ No CAS ]
  • 3
  • [ 558478-81-2 ]
  • [ 3383-21-9 ]
  • 5,7-Ditert-butyl-1-cyclopropyl-1,2,3,3a-tetrahydrobenzo[d]pyrrolo[2,1-b]-oxazole [ No CAS ]
  • 4
  • 2,4-di-tert-butyl-6-(2-cyclopropylpyrrolidin-1-yl)phenol [ No CAS ]
  • [ 558478-81-2 ]
  • [ 3383-21-9 ]
  • 5
  • [ 3383-21-9 ]
  • [ 134855-87-1 ]
  • 4-(6,8-di-tert-butyl-2H-benzo[b][1,4]oxazin-3-yl)phenol [ No CAS ]
  • 6
  • [ 3383-21-9 ]
  • [ 134855-87-1 ]
  • C22H29NO2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile; at 20℃;Inert atmosphere; General procedure: To a stirred solution of ortho-benzoquinone (0.825 mmol, 1.0equiv) in acetonitrile (4.0 mL), was added dropwise a solution ofprimary amine (0.825 mmol, 1.0 equiv) in acetonitrile (4.25 mL)over 5 min under an argon atmosphere. The deep green colouredsolution was stirred at room temperature for 2e8 h. Aftercompletion of the reaction, as indicated by TLC, the reactionmixture was cooled to 0C. To this, triethylamine (0.34 mL,2.48 mmol, 3 equiv) and iodine granules (0.419 g, 1.65 mmol, 2 eq),were added. The resulting mixture was stirred vigorously for10e60 min under argon atmosphere. Upon completion, the reac-tion mixture was diluted with water and extracted with EtOAc(3 5 mL). The combined organic layer was washed with aqueoussaturated sodium thiosulfate (1 10 mL) and brine (2 10 mL),respectively, dried over Na2SO4, ltered, and concentrated in vacuo.The crude residue was puried by silica gel column chromatog-raphy eluting with pentane:EtOAc (95:5e80:20 v:v) to afford thedesired benzo[1,4]oxazine product.
 

Historical Records

Technical Information

Categories