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Chemical Structure| 3029-19-4 Chemical Structure| 3029-19-4
Chemical Structure| 3029-19-4

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3-Pyrenylaldehyde is a pyrene-based compound with strong fluorescence, used in molecular probe studies.

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Product Details of 3-Pyrenylaldehyde

CAS No. :3029-19-4
Formula : C17H10O
M.W : 230.26
SMILES Code : O=CC1=C(C2=C34)C=CC4=CC=CC3=CC=C2C=C1
MDL No. :MFCD00004139
InChI Key :RCYFOPUXRMOLQM-UHFFFAOYSA-N
Pubchem ID :232848

Safety of 3-Pyrenylaldehyde

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of 3-Pyrenylaldehyde

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3029-19-4 ]

[ 3029-19-4 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 13754-19-3 ]
  • [ 3029-19-4 ]
  • [ 1426931-11-4 ]
  • 2
  • [ 3029-19-4 ]
  • [ 57497-39-9 ]
  • [ 1542212-85-0 ]
  • 3
  • [ 3029-19-4 ]
  • [ 54396-44-0 ]
  • [ 868-85-9 ]
  • dimethyl (2-methyl-3-(trifluoromethyl)phenylamino)(pyren-1-yl)methylphosphonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
97% With chitosan; In neat (no solvent); at 75℃; for 0.0333333h;Microwave irradiation; Green chemistry; General procedure: An equimolar mixture of <strong>[54396-44-0]2-methyl-3-(trifluoromethyl)aniline</strong> (0.351 g, 0.002 mol), corresponding aldehyde (0.002 mol), dimethyl phosphite (0.18 ml, 0.002 mol) and chitosan catalyst (10 molpercent) were taken in a reaction glass tube, degassed for 10 min and microwave irradiated at 180 W for 2 min at 60 °C. The progress of the reaction was monitored by TLC using petroleum ether and ethyl acetate (3:7) as solvent. After completion of the reaction, the mixture was diluted with ethyl acetate, washed with water (2 x 15 ml) followed by brine (1 x 10 ml), dried over Na2SO4 and evaporated to dryness. The crude mass was purified by column chromatography on silicagel (100-200 mesh) by using a 7:3 mixture of ethyl acetate in hexane to afford the pure alpha-aminophosphonates.
  • 4
  • [ 3029-19-4 ]
  • [ 1671-88-1 ]
  • (pyrene-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine [ No CAS ]
YieldReaction ConditionsOperation in experiment
54% With acetic acid; In methanol; at 85℃; for 6h; 1.20 mmol of 1-pyrene monoaldehyde and1.00 mmol of 3,5-dipyridyl-4-amino-1,2,4-triazole was added to100 ml three-necked round bottom flask containing 20 ml of methanol.Under magnetic stirring,Slowly heated to 85 C,When all the ingredients are completely dissolved,Slowly add 3 drops of glacial acetic acid.The reaction was stopped after stirring for 6h at 85 C.The resulting reaction solution was cooled to room temperature,That is, yellow precipitate precipitation,filter,Washed three times with methanol,After drying that get L3,Yield 54%.
 

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