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Structure of 2785-06-0

Chemical Structure| 2785-06-0

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Product Details of [ 2785-06-0 ]

CAS No. :2785-06-0
Formula : C9H10INS
M.W : 291.15
SMILES Code : C[N+]1=C(C)SC2=CC=CC=C12.[I-]
MDL No. :MFCD00031760
InChI Key :VZRIFNLQJXPRJI-UHFFFAOYSA-M
Pubchem ID :459121

Safety of [ 2785-06-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 2785-06-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2785-06-0 ]

[ 2785-06-0 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 33985-71-6 ]
  • [ 2785-06-0 ]
  • [ 1401522-24-4 ]
YieldReaction ConditionsOperation in experiment
85% With pyridine; In methanol; for 12h;Reflux; To the solution of 2,3-dimethylbenzothiazolium iodide (0.87 g, 0.003 mol) in methanol (15 mL), 9-(julolidinyl)carbaldehyde (0.6 g, 0.003 mol) and a few drops of pyridine were added. The reaction mixture was heated to reflux for 12 h. The dark precipitate with metallic lustre was filtered off and washed with diethyl ether. Yield: 1.2 g (85%); mp 233-234 C. IR (powder film): nu = 3425 (-OH in CH3OH, H-bonded), 3058 and 3012 (=C-H, CAr-H), 2933 and 2841 and 2706 and 2609 (Csp3-H), 1617 and 1569 (C=C, CAr=CAr), 1518, 1494, 1453, 1315, 1293, 1157 cm-1. 1H NMR ((CD3)2SO, 600 MHz): delta = 8.23 (d, J = 7.8 Hz, 1H, CAr-H), 8.01 (d, J = 7.8 Hz, 1H, CAr-H), 7.88 (d, J = 15.0 Hz, 1H, CH=), 7.74 (dt, J = 7.8 Hz, J = 0.9 Hz, 1H, CAr-H), 7.63 (dt, J = 7.8 Hz, J = 0.9 Hz, 1H, CAr-H), 7.44 (d, J = 15.0 Hz, 1H, CH=), 4.16 (s, 3H, N+-CH3), 3.37 (t, J = 5.9 Hz, 4H, CH2), 2.73 (t, J = 5.8 Hz, 4H, CH2), 1.92-1.88 (m, 4H, CH2). 13C NMR ((CD3)2SO,) 129.1, 127.4, 126.9, 124.1, 121.6, 121.0 (2 × C), 115.9, 104.6, 50.1 (2 × C), 35.6, 27.4 (2 × C), 21.1 (2 × C). 15N NMR ((CD3)2SO, 600 MHz): delta = -212.2, -289.4.
  • 2
  • [ 2785-06-0 ]
  • [ 24372-46-1 ]
  • 2-((E)-2-[5-N,N-dimethylthiophen]vinyl)-3-methyl-1,3-benzothiazol-3-ium iodide [ No CAS ]
YieldReaction ConditionsOperation in experiment
13% With piperidine; In ethanol; for 6.0h;Reflux; General procedure: A solution of aldehyde 2a-f (1mmol), benzothiazolium salt 1 (1mmol) and piperidine (1 drop) in ethanol (10ml) was heated at reflux for 6h. After this time the solid that precipitated from the reaction mixture was filtered and washed with cold ethanol to give the pure products.
 

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