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Chemical Structure| 23950-59-6 Chemical Structure| 23950-59-6

Structure of 23950-59-6

Chemical Structure| 23950-59-6

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Product Details of [ 23950-59-6 ]

CAS No. :23950-59-6
Formula : C7H3Br2ClO
M.W : 298.36
SMILES Code : O=C(Cl)C1=CC(Br)=CC(Br)=C1
MDL No. :MFCD12025232

Safety of [ 23950-59-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H314
Precautionary Statements:P264-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P403+P233-P501
Class:8
UN#:3265
Packing Group:

Application In Synthesis of [ 23950-59-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 23950-59-6 ]

[ 23950-59-6 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 24973-50-0 ]
  • [ 23950-59-6 ]
  • [ 7647-18-9 ]
  • 2-(3,5-dibromophenyl)-4,6-bis(biphenyl-3-yl)-oxa-3,5-diadinium hexachoroantimonate (V) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In chloroform; at 0℃;Reflux; Inert atmosphere; Reference Example 7 Synthesis of 2-(3,5-dibromophenyl)-4,6-bis(biphenyl-3-yl)-1,3,5-triazine 4.1 g of 3,5-dibromobenzoyl chloride and 5.0 g of <strong>[24973-50-0]3-phenylbenzonitrile</strong> were dissolved in 100 mL of chloroform in an argon atmosphere. To the thus-obtained solution, 4.2 g of antimony pentachloride was dropwise added at 0C. The resultant mixture was stirred at room temperature for 1 hour, and then refluxed for 12 hours. Thereafter the mixture was cooled to room temperature, and then low boilng point components were removed under a reduced pressure to give 2-(3,5-dibromophenyl)-4,6-bis(biphenyl-3-yl)-oxa-3, 5-diadinium hexachoroantimonate (V) as a red solid.
  • 2
  • [ 24973-50-0 ]
  • [ 23950-59-6 ]
  • C33H21Br2N2O(1+)*Cl6Sb(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With antimonypentachloride; In chlorobenzene; at 0℃;Reflux; 4.10 g of 3,5-dibromobenzoyl chloride and 5.00 g of 3-biphenylcarbonitrile were dissolved in 100 mL of chloroform in a stream of argon. The obtained solution was cooled to 0C, and 4.20 g of antimony pentachloride was added dropwise to the cooled solution. The obtained mixed liquid was stirred at room temperature for 1 hour, and then, heated under reflux for 12 hours. The obtained reaction mixture was cooled to room temperature, and then distilled under a reduced pressure to remove all volatile materials to give a red solid. The obtained red solid was pulverized in a stream of argon and added to aqueous 28% ammonia maintained at 0C. The thus-obtained suspension was further stirred at room temperature for 1 hour and then filtered. The obtained precipitate was washed with water and then with methanol. The thus-obtained precipitate was dried, and then subjected to extraction using a soxhlet extractor and chloroform as extracting solvent. The extracted liquid was left to stand to be thereby cooled, and the deposited solid was collected by filtration. The obtained solid was dried to give 2.80 g of 4,6-bis(3-biphenylyl)-2- (3,5-dbromophenyl) -1,3,5-triazine as a white powder (yield: 32%) . 1H-NMR(CDCl3):57.46(brt,J=7.4Hz,2H),7.52-7.58(m,4H),7,67 (dd,J=7.8Hz,7.7Hz,2H),7.76(brd,J=7.7Hz,4H),7.86(d,J=7.7Hz,2H), 7.90(brd,1H),8.72(d,J=7.8Hz,2H),8.81(d,J=1.8Hz,2H),8.95(s,2H). 13C-NMR(CDCl3):δ123.4,127.4,127.4,127.7,128.8,128.1,130.7,131.7, 136.2,137.7,139.7,140.7,141.9,169.4,172.0.
  • 3
  • [ 24973-50-0 ]
  • [ 23950-59-6 ]
  • [ 7647-18-9 ]
  • C33H21Br2N3*Cl6Sb(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In chloroform; at 0 - 20℃; for 13h;Inert atmosphere; Reflux; 4.10 g of 3,5-dibromobenzoic acid chloride and 5.00 g of 3-biphenylcarbonitrile were dissolved in 100 mL of chloroform in a stream of argon. The thus-obtained solution was cooled to 0C, and then 4.20 g of antimony pentachloride was dropwise added therein. The mixture was stirred at room temperature for one hour, and then heated under reflux for 12 hours. The reaction mixture was cooled to room temperature, and then distilled under a reduced pressure thereby removing low-boiling point ingredients to give a red solid.
 

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