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Chemical Structure| 23159-87-7 Chemical Structure| 23159-87-7

Structure of 23159-87-7

Chemical Structure| 23159-87-7

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2-Bromo-6-(tert-butyl)phenol

CAS No.: 23159-87-7

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Cat. No.: A1184706 Purity: 95%

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Product Details of [ 23159-87-7 ]

CAS No. :23159-87-7
Formula : C10H13BrO
M.W : 229.11
SMILES Code : OC1=C(C=CC=C1Br)C(C)(C)C
MDL No. :MFCD16996888
InChI Key :AXYXIQJROSLHJZ-UHFFFAOYSA-N
Pubchem ID :12334673

Safety of [ 23159-87-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501

Application In Synthesis of [ 23159-87-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 23159-87-7 ]

[ 23159-87-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 88-18-6 ]
  • [ 23159-87-7 ]
  • [ 10323-39-4 ]
YieldReaction ConditionsOperation in experiment
With vanadate(V)-dependent bromoperoxidase I from Ascophyllum nodosum; dihydrogen peroxide; sodium bromide; In water; tert-butyl alcohol; at 23℃; for 72h;pH 6.2;Enzymatic reaction; General procedure: A solution of H2O2 (1.0 mL, 0.825 M) and NaBr (77.2 mg, 0.75 mmol) in MES-buffer (500 mM, pH 6.2) was added with a syringe pump (8 h, 2.08 mL/min) to a solution of substrate 1, or 8 (0.75 mmol) and VBrPO(AnI) [55.2 mL (0.5626 mg/mL; 558 UT/mg), 17.3 UT, 0.036 mmol% for 1a, 1c, and 8; 62.8 mL (0.4505 mg/mL; 611 UT/mg), 17.3 UT, 0.031 mmol% for 1b and 1d-f] in MES-buffer (500 mM, pH 6.2, 10.0 mL) and tBuOH (3.3 mL). The reaction mixturewas stirred at 23 C for 3 d. The aqueous layer was extracted with Et2O (4*10 mL). Combined organic extracts were dried (MgSO4). The solvent was removed under reduced pressure (14 mbar, 40 C) to afford a product mixture, whichwas analyzed by 1H NMR or GC, using pentachlorobenzene (1H NMR, 1aed and), 1- bromodecane (1H NMR, for 1e), or n-decane (GC, for 8) as an internal standard in comparison to spectroscopic data from authentic references. pH and bromoperoxidase activity (triiodide assay35)were determined from the aqueous layer.
  • 2
  • [ 88-18-6 ]
  • [ 23159-87-7 ]
  • [ 15460-12-5 ]
  • [ 10323-39-4 ]
 

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