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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 2177-70-0 Chemical Structure| 2177-70-0
Chemical Structure| 2177-70-0

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Product Details of Phenyl methacrylate

CAS No. :2177-70-0
Formula : C10H10O2
M.W : 162.18
SMILES Code : CC(C(OC1=CC=CC=C1)=O)=C
MDL No. :MFCD00048117
InChI Key :QIWKUEJZZCOPFV-UHFFFAOYSA-N
Pubchem ID :75121

Safety of Phenyl methacrylate

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338
Class:3
UN#:3272
Packing Group:

Application In Synthesis of Phenyl methacrylate

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2177-70-0 ]

[ 2177-70-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 645-67-0 ]
  • [ 2177-70-0 ]
  • C15H18O4 [ No CAS ]
  • C15H18O4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With copper(II) acetate hydrate; C43H39FeNP2; In toluene;Inert atmosphere; Under nitrogen protection,Taniaphos ligand L3 (R4=R5=Ph) (5.3 mg) was added to the dry reaction flask.Cu(OAc)2·H2O (3.0 mg), toluene (1.0 mL),Polymethylhydrogensiloxane (100μL),Stir thoroughly. To the above mixture, phenyl methacrylate (200 μL) was added dropwise with stirring.A solution of propyl 3- levulinate (128 mg) in toluene (4.0 mL),After the addition was complete, the reaction was stirred overnight. Saturated aqueous NH4F solution (2 mL) was added to the reaction mixture.After stirring for 30 min, the phases were separated and the aqueous phase was extracted with dichloromethane (3 x 5 mL).The combined organic phases are washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated.After column chromatography, γ-methyl-γ-(1-methyl-1-phenoxycarbonylethyl)-γ-cyclobutyrolactone (203 mg, yield 77%, ee value) was obtained as a colorless oily liquid. 16%).
 

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