Home Cart Sign in  
Chemical Structure| 21190-35-2 Chemical Structure| 21190-35-2

Structure of 21190-35-2

Chemical Structure| 21190-35-2

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 21190-35-2 ]

CAS No. :21190-35-2
Formula : C11H16O
M.W : 164.24
SMILES Code : OCC1=CC=CC=C1C(C)(C)C
MDL No. :MFCD15527515

Safety of [ 21190-35-2 ]

Application In Synthesis of [ 21190-35-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 21190-35-2 ]

[ 21190-35-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1077-58-3 ]
  • [ 21190-35-2 ]
YieldReaction ConditionsOperation in experiment
942 mg To a solution of <strong>[1077-58-3]2-tert-butylbenzoic acid</strong> (1.00 g) in THF(20 mL) was added 1.0M borane THF complex THF solution (16.8 mL) under ice-cooling. The reaction mixture was stirred at room temperature overnight under a nitrogen atmosphere, IN aqueous sodium hydroxide solution was added, and the mixture was extracted with ethyl acetate. The extract was dried over anhydrous magnesium sulfate, and the solvent was evaporated under reduced pressure. The residue was purified by silica gel column chromatography (ethyl acetate/hexane) to give the title compound (942 mg) .XH NMR (300 MHz, DMSO-d6) δ 1.35 (9H, s) , 4.70 (2H, d, J = 5.4 Hz), 5.10 (1H, t, J = 5.4 Hz), 7.12-7.22 (2H, m) , 7.27-7.34 (1H, m) , 7.48-7.55 (1H, m) .
  • 2
  • [ 21190-35-2 ]
  • 3-Amino-6-(2-t-butylbenzyloxy)pyridazine [ No CAS ]
  • [ 1077-58-3 ]
YieldReaction ConditionsOperation in experiment
3-Amino-6-(2-t-butylbenzyloxy)pyridazine From 2-t-butylbenzyl alcohol to give title compound mp. 147-9 δH(DMSO) 7.4(2H,m,ArH), 7.28(2H,m,ArH), 6.9(1H,JAB,8 Hz,4H), 6.85(1H,JAB,8 Hz,5H), 6.0(2H,brs,NH2), 5.5(2H,s,CH2), 1.4(9H,s,Me3). (Alcohol prepared by LAH reduction of 2-t-butylbenzoic acid; M. Crawford and F. H. C. Stewart, J. Chem. Soc., 1952, 4444).
 

Historical Records