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Chemical Structure| 2039-83-0 Chemical Structure| 2039-83-0

Structure of 2039-83-0

Chemical Structure| 2039-83-0

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Product Details of [ 2039-83-0 ]

CAS No. :2039-83-0
Formula : C8H6Cl2
M.W : 173.04
SMILES Code : C=CC1=CC=C(Cl)C(Cl)=C1
MDL No. :MFCD00013625
InChI Key :BJQFWAQRPATHTR-UHFFFAOYSA-N
Pubchem ID :74869

Safety of [ 2039-83-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of [ 2039-83-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2039-83-0 ]

[ 2039-83-0 ] Synthesis Path-Downstream   1~35

  • 1
  • [ 491-35-0 ]
  • [ 7312-27-8 ]
  • [ 2039-83-0 ]
  • 3
  • [ 16218-28-3 ]
  • [ 2039-83-0 ]
  • [ 51119-29-0 ]
  • 4
  • [ 2039-83-0 ]
  • [ 55978-57-9 ]
  • 5
  • [ 2039-83-0 ]
  • [ 51-44-5 ]
  • [ 42981-08-8 ]
  • [ 91309-68-1 ]
  • [ 91309-69-2 ]
  • 6
  • [ 2039-83-0 ]
  • [ 42981-08-8 ]
  • [ 113337-38-5 ]
  • [ 91309-68-1 ]
  • [ 91309-69-2 ]
  • 7
  • [ 2039-83-0 ]
  • [ 42981-08-8 ]
  • [ 91309-68-1 ]
  • [ 91309-69-2 ]
  • [ 6287-38-3 ]
  • 9
  • [ 136272-23-6 ]
  • [ 2039-83-0 ]
  • [ 76-05-1 ]
  • 10
  • [ 74-85-1 ]
  • [ 3024-72-4 ]
  • [ 2039-83-0 ]
  • 11
  • [ 2039-83-0 ]
  • [ 52147-99-6 ]
  • 13
  • [ 1475-11-2 ]
  • [ 2039-83-0 ]
  • 25
  • (+-)-3.4-dichloro-<1-acetoxy-ethyl>-benzene [ No CAS ]
  • [ 2039-83-0 ]
  • 26
  • polystyrene [ No CAS ]
  • [ 2039-83-0 ]
  • 33
  • [ 2039-83-0 ]
  • [ 141303-34-6 ]
  • [ 256474-26-7 ]
YieldReaction ConditionsOperation in experiment
With (S)-N-((R)-3,3-dimethylbutan-2-yl)-3,3-dimethyl-2-(((1-methyl-1H-imidazol-2-yl)methyl)amino)butanamide; iron(III) chloride hexahydrate; dihydrogen peroxide; In tert-Amyl alcohol; water; at 20℃; for 1h; General procedure: To a solution of FeCl3 6 H2O (6.8 mg, 25.0 mumol, 5 mol%) in 9 mL 2-Me-2-BuOH, an imidazole basedligand (50.0 mumol, 10 mol%) was added at room temperature under air. After addition of the olefin (500mumol), H2O2 (30 wt% in H2O, 170 muL, 1.50 mmol) mixed with 830 muL 2-Me-2-BuOH was added via syringepump over a 1 h period. The reaction was quenched with 50 muL saturated aqueous Na2SO3 solution. Afterextraction with CH2Cl2, the organic phases were combined and evaporated to dryness. The crude mixture was filtered through a SiO2-plug (1 cm, eluted with CH2Cl2). In order to determine the yield via 1H-NMR,pyrazine was added in a defined amount as an internal standard. Afterwards, purification was carriedout by means a preparative TLC plate (hexane/ethyl acetate) for the HPLC sample preparation in orderto determine enantioselectivity.
  • 34
  • [ 2039-83-0 ]
  • 9-(3,4-dichloro-phenyl)-7-ethyl-6,7,8,9-tetrahydro-5<i>H</i>-10-thia-7-aza-benzo[<i>a</i>]azulene [ No CAS ]
  • 35
  • [ 2039-83-0 ]
  • [ 215594-40-4 ]
 

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