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Chemical Structure| 19781-77-2 Chemical Structure| 19781-77-2

Structure of 19781-77-2

Chemical Structure| 19781-77-2

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Product Details of [ 19781-77-2 ]

CAS No. :19781-77-2
Formula : C7H14O
M.W : 114.19
SMILES Code : CCC(O)CCC=C
MDL No. :MFCD00046683

Safety of [ 19781-77-2 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H315-H319-H335
Precautionary Statements:P210-P240-P242-P243-P261-P264-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P363-P370+P378-P403+P233-P501
Class:3
UN#:1987
Packing Group:

Application In Synthesis of [ 19781-77-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 19781-77-2 ]

[ 19781-77-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 19781-77-2 ]
  • [ 6608-47-5 ]
  • hept-6-en-3-yl ethenesulfonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% With TEA; In dichloromethane; at -78 - 0℃;Inert atmosphere; General procedure: A solution of the unsaturated alcohol (7a,b) (1.0 equiv.) and dry TEA (1.5equiv.) in CH2Cl2 was stirred at low temperature (-40-0 oC) under inert atmosphere in two necked flask. Asolution of 2-chloroethanesulfonyl chloride (1.3-1.5 equiv.) in CH2Cl2was then added drop by drop. Thereaction mixture left to stir under this temperature for 3-7 h. then diluted with pentane and filtered throughCelite. The filtrate was concentrated under reduced pressure and the crud residue was purified by flashchromatography.
 

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