Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 1772-25-4 Chemical Structure| 1772-25-4

Structure of 1772-25-4

Chemical Structure| 1772-25-4

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Product Citations      Show More

Mathison, Ricardo ; Rani, Elina ; Rose, Amelia M ; Prendi, Fjona ; Bloomquist, Casey K ; Modestino, Miguel A

Abstract: Organic electrosynthesis using renewable electricity offers a sustainable approach to chemical manufacturing. Among its promising applications, the selective transformation of complex organic mixtures presents a valuable opportunity to eliminate costly separation processes and directly convert heterogeneous feedstocks into valuable products. However, controlling selectivity in mixed reaction mixtures remains challenging due to competing reaction pathways and varying reactivities among substrates. Here, we demonstrate how selectivity in mixed organic electrosynthesis can be systematically controlled through the balance of reaction kinetics and mass transport limitations. Using acrylonitrile and crotononitrile mixtures as a model substrate mixture, we established quantitative relationships between substrate compositions, current densities, and product distributions that reveal distinct kinetically-limited and mass transport-limited reaction regimes control selectivity. We further demonstrated how pulsed electrolysis can be used to strategically control these reaction regimes to drive selectivity towards specific products. These insights create opportunities for developing adaptive and dynamic chemical manufacturing processes capable of handling complex feedstocks.

Purchased from AmBeed:

Mathison, Ricardo ; Atwi, Rasha ; McConnell, Hannah B ; Ochoa, Emilio ; Rani, Elina ; Akashige, Toshihiro , et al.

Abstract: Electrosynthesis at an industrial scale offers an opportunity to use renewable electricity in chemical manufacturing, accelerating the decarbonization of large-scale chemical processes. Organic electrosynthesis can improve product selectivity, reduce reaction steps, and minimize waste byproducts. Electrochemical synthesis of adiponitrile (ADN) via hydrodimerization of acrylonitrile (AN) is a prominent example of industrial organic electrochemical processes. It circumvents the drawbacks of thermochemical synthesis by reducing toxicity and leveraging clean electricity as an energy source. Despite its industrial importance, mechanistic understanding and experimental insights on the near-electrode molecular processes of AN electrohydrodimerization remain insufficient. Here we show, using in-situ ATR-FTIR spectroscopy, that tetraalkylammonium ions populate the electrical double layer (EDL), creating a microenvironment that favors interactions with organic molecules and enhances AN concentration while expelling water molecules. Our results provide experimental evidence supporting long-standing mechanistic hypotheses. Kinetic isotope effect studies reveal that propionitrile (PN) formation is rate-limited by proton transfer, while ADN formation likely is not. Electron paramagnetic resonance spectroscopy confirms the presence of free radicals during AN electroreduction, suggesting that coupling of PN radicals occurs primarily in the electrolyte. These insights highlight the importance of carefully controlling the EDL composition for selective organic electrosynthesis and provide fundamental engineering guidance for designing high-performing electro-organic reactions. We anticipate these findings will guide the optimization of electrolyte formulations and electrode interfaces for ADN synthesis and other emerging electro-organic processes.

Keywords: organic electrosynthesis ; mechanistic insights ; interfacial environments ; adiponitrile electrosynthesis ; sustainability

Purchased from AmBeed: ;

Alternative Products

Product Details of [ 1772-25-4 ]

CAS No. :1772-25-4
Formula : C9H11N3
M.W : 161.20
SMILES Code : N#CCCC(C#N)CCCC#N
MDL No. :MFCD00129792
InChI Key :LNLFLMCWDHZINJ-UHFFFAOYSA-N
Pubchem ID :15678

Safety of [ 1772-25-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H227-H301+H311+H331-H315-H319
Precautionary Statements:P210-P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P370+P378-P403+P233-P405-P501
Class:6.1
UN#:3276
Packing Group:
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 1772-25-4 ]

Aliphatic Chain Hydrocarbons

Chemical Structure| 4553-62-2

A294172 [4553-62-2]

2-Methylglutaronitrile

Similarity: 1.00

Chemical Structure| 830319-38-5

A378778 [830319-38-5]

2-Decylsuccinonitrile

Similarity: 1.00

Chemical Structure| 55897-64-8

A294675 [55897-64-8]

2-Isopropyl-2,3-dimethyl-butyronitrile

Similarity: 0.93

Chemical Structure| 80822-82-8

A457177 [80822-82-8]

2,3-Diisobutyl-2,3-dimethylsuccinonitrile

Similarity: 0.93

Nitriles

Chemical Structure| 32730-85-1

A728427 [32730-85-1]

Cycloheptanecarbonitrile

Similarity: 1.00

Chemical Structure| 830319-38-5

A378778 [830319-38-5]

2-Decylsuccinonitrile

Similarity: 1.00

Chemical Structure| 13310-75-3

A751450 [13310-75-3]

2-Propylvaleronitrile

Similarity: 1.00

Chemical Structure| 617-80-1

A350858 [617-80-1]

2-Ethylbutanenitrile

Similarity: 1.00

Chemical Structure| 4379-04-8

A1145290 [4379-04-8]

Pentane-1,3,5-tricarbonitrile

Similarity: 1.00