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CAS No. : | 174501-65-6 | MDL No. : | MFCD03095449 |
Formula : | C8H15BF4N2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | LSBXQLQATZTAPE-UHFFFAOYSA-N |
M.W : | 226.02 | Pubchem ID : | 2734178 |
Synonyms : |
|
Num. heavy atoms : | 15 |
Num. arom. heavy atoms : | 5 |
Fraction Csp3 : | 0.62 |
Num. rotatable bonds : | 3 |
Num. H-bond acceptors : | 4.0 |
Num. H-bond donors : | 0.0 |
Molar Refractivity : | 53.89 |
TPSA : | 8.81 Ų |
GI absorption : | High |
BBB permeant : | Yes |
P-gp substrate : | No |
CYP1A2 inhibitor : | No |
CYP2C19 inhibitor : | No |
CYP2C9 inhibitor : | No |
CYP2D6 inhibitor : | No |
CYP3A4 inhibitor : | No |
Log Kp (skin permeation) : | -5.16 cm/s |
Log Po/w (iLOGP) : | 0.0 |
Log Po/w (XLOGP3) : | 3.55 |
Log Po/w (WLOGP) : | 4.09 |
Log Po/w (MLOGP) : | 1.63 |
Log Po/w (SILICOS-IT) : | 0.89 |
Consensus Log Po/w : | 2.03 |
Lipinski : | 0.0 |
Ghose : | None |
Veber : | 0.0 |
Egan : | 0.0 |
Muegge : | 0.0 |
Bioavailability Score : | 0.55 |
Log S (ESOL) : | -3.53 |
Solubility : | 0.0672 mg/ml ; 0.000298 mol/l |
Class : | Soluble |
Log S (Ali) : | -3.42 |
Solubility : | 0.0859 mg/ml ; 0.00038 mol/l |
Class : | Soluble |
Log S (SILICOS-IT) : | -1.55 |
Solubility : | 6.4 mg/ml ; 0.0283 mol/l |
Class : | Soluble |
PAINS : | 0.0 alert |
Brenk : | 2.0 alert |
Leadlikeness : | 2.0 |
Synthetic accessibility : | 1.67 |
Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P273-P301+P310-P305+P351+P338 | UN#: | 2810 |
Hazard Statements: | H301-H315-H319-H411 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99% | The NHC-BMIm-BF4 or NHC-CO2-BMIm-BF4 solution was added to 0.5mmol of elemental sulfur and the mixture subjected to ultrasound irradiation (4W) for 10min. Then usual workup [49] gave the product in the yields reported in Table 1. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
84% | In einen 2 I Schlenkkolben werden 620,5 g (5 mol) 1-Butylimidazol vorgelegt und 630,6 g (5 mol) Dimethylsulfat portionsweise zugegeben. Der Ansatz wird danach 15 Minuten nachgeruehrt. Der Kolbeninhalt wirdin ein 5l Becherglas ueberfuehrt und zu einer Mischung von 548,0 g (5 mol) Natriumtetrafluoroborat in 2 Liter Wasser gegeben. Die waessrige Phase wird nun viermal mit je 1 Liter CH2Cl2extrahiert, die organischen Phasen vereinigt und von Methylenchlorid befreit. Das Produkt wird ueber Nacht bei 60C am HV getrocknet. Man erhaelt 1-Butyl-3-methylimidazolium tetrafluoroborat in 84 %iger Ausbeute. Zum qualitativen Nachweis auf Chloridreste, werden ca. 1 ml des Produktes mit ca. 5 ml Wasser versetzt und mit 2 Tropfen konzentrierter Salpetersaeure angesaeuert. Zu dieser Loesung werden dann ca. 3-4 Tropfen Silbernitrat gegeben um etwaig vorhandenes Chlorid als Silberchlorid auszufaellen. Das Ausbleiben eines Silberchlorid-Niederschlags spricht fuer die komplette Abwesenheit von Chloridresten. 1H-NMR (300 MHz, CDCl3):0,79 (3 H, tr, J=5,8 Hz, Ha); 1,22 (2 H, m, Hb); 1,74 (2 H, m, Hc); 3,86 (3 H, s, Hh); 4,17 (2 H, tr, J=5,8 Hz, Hd); 7,51; 7,57 (je 1 H, s, Hf,g); 8,7 (1 H, s, He).13C-NMR (75 MHz, CDCl3):14,1 (a); 20,3-36,8 (b, c, d); 50,4 (h); 123,2-125,0 (f,g); 137,8 (e).19F-NMR (281 MHz, CDCl3):148,5-150,8 (m) |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | In einem Autoklaven wurden 0,5 Mol 1-Butylimidazol (Fa. Aldrich) und 0,6 Mol Dimethylcarbonal in 50 g Methanol 12 Stunden bei 135C geruehrt. Der abgekuehlte Austrag wurde im Vakuum vom Loesungsmittel und nicht-umgesetzten Edukten befreit. Es wurden 0,5 Mol Tetraflourborsaeure in Diethylether (Fa. Aldrich) zugegeben, 2 Stunden geruehrt und die Reaktionsmischung dann im Vakuum von Loesungsmittelresten befreit Es wurden 0,34 Mol 1-Butyl-3-methylimdazoliumtetrafluoroborat, im Folgenden vereinfacht als [BMIM] [BF4] bezeichnet, erhalten (68 % d.Th.). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | With sodium tetrafluoroborate; In acetone; for 14h; | 70 G of 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE WAS ADDED TO 150 ML OF acetone, and 57 g (1.1 eq. ) of sodium tetrafluoroborate was added thereto and reacted for 24 hours, followed by filtering the reactant solution to remove salts. The resulting filtrate was distilled to remove acetone, giving an unpurified 1- BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE IONIC LIQUID. To the unpurified 1-BUTL-3-METHYLIMIDAZOLIUM TETRAFTUOROBORATE ionic liquid was added ionic water to prepare a product having a concentration of about 50%, followed by transferring to a reflux device of the continuous distillation extraction apparatus. Then, methylene chloride was added to a receiver (3V/W) and REFLUXED AT 39 ~ 40C FOR ABOUT 24 HOURS. Then, the methylene chloride solution was collected from the receiver of the continuous distillation extraction apparatus and methylene chloride was distilled to be removed, followed by drying under reduced pressure at 60C for 76 hours to remove water, thereby acquiring a desired ionic liquid, 1-butyl-3- methylimidazolium tetrafluoroborate ionic liquid. Yield : 100 g (93%), residual chloride ions: 2-20 ppm (before purification: 3500 ppm), residual sodium ions: 1-5 ppm (before purification: 300 ppm), water: 500 ppm. To achieve high purity ionic liquids, the obtained 1-BUTYL-3- methylimidazolium tetrafluoroborate ionic liquid was repeatedly purified. Yield : 95 g (95%), residual chloride ions: 1-5 ppm (before repeated cycles of purification: 2-20 ppm), residual sodium ions < 3 ppm (before repeated cycles of purification: 1 No. 5 ppm), water: 500 ppm. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
, wherein said salt is selected from the group consisting of: ... 4-methyl-N-butylpyridinium chloride, 3-methyl-N-butylpyridinium chloride, 4-methyl-N-hexylpyridinium chloride, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-pentyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium tetrafluoroborate, 1-heptyl-3-methylimidazolium tetrafluoroborate, ... |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86.7% | In acetone; at 20℃; for 48h; | The intermediate [Bmim] Cl50g withSodium borofluoride(According to the ratio of its mass is 1: 1.05)Join a three-necked flask with a stirring device,100mL acetone as the reaction medium,Mechanical stirring at room temperature 48h, suction filtration (acetone washing) to remove NaCl,Rotate to acetone, and then add CH2C12 wash,Swirl to remove CH2C12,The resulting ionic liquid was dried in a vacuum oven at 80 24hAfter the pale yellow transparent liquid 56.3g:which isl-Butyl-3-methylimidazolium tetrafluoroborateIonic Liquid ([Bmim]BF4) in a yield of 86.7%. |
85.1% | In acetone; at 20℃; for 48h; | The intermediate product [Bmim] Cl 87g was mixed with sodium fluoroborate (1: 1.05 in terms of its mass ratio)Was added to a three-necked flask equipped with a stirrer,To l0mL acetone as the reaction medium, room temperature mechanical stirring 48h,Pumping (acetone wash) to remove NaCl,Steamed to acetone, then add CH2C12 washing,The CH2C12 was removed by steaming and the resulting ionic liquid was dried in a vacuum oven at 80 C for 24 hAfter the light yellow transparent liquid 96.2g:Namely 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid([Bmim] BF4) in a yield of 85.1%. |
85.4% | In acetone; at 20℃; for 48h; | The intermediate [Bmim] Cl 50g and sodium borofluoride (according to the ratio of its mass of 1: 1.05) was added to a three-necked flask equipped with a stirring device,100mL acetone as the reaction medium,Mechanical stirring at room temperature 48h,Suction filtration (acetone wash) to remove NaCl,Rotate to acetone,Then add CH2C12 washing,Swirl to remove CH2C12,The resulting ionic liquid was dried in a vacuum oven at 80 C for 24 hours to obtain 55.5g of light yellow transparent liquid: l-butyl-3-methylimidazolium tetrafluoroborate ionic liquid ([Bmim] BF4)Yield 85.4%. |
80% | In water; at 25 - 80℃; under 0.000750075 Torr; for 10.5h; | (1) at room temperature about 25 o C lower, will 103g sodium four fluorine boron (NaBF 4) is added to 100 ml of deionized water, 500 ml flask, mechanical stirring 30 minutes, so as to form saturated NaBF 4 aqueous solution, with a small amount of solid remaining at the bottom of the; (2) in the above-mentioned saturated solution continue adding 0.5mol/55gNaBF 4 and 0.5mol/87 g1-butyl-3-methyl imidazole chlorine salt BMImCl; (3) mechanical stirring 30 minutes, the full reaction; (4) standstill after the reaction, the solution is divided into three layers: the upper layer is mainly ionic liquid BMImBF 4, the middle layer is a saturated aqueous solution, the bottom layer is mainly solid inorganic salt NaCl by-product, is transferred to the solution in the separatory funnel, the remaining bottom layer for NaCl solid non-polar by-products. (5) solution of layering in the separatory funnel, the upper layer of the ionic liquid solution, the lower is the saturated aqueous solution, with the liquid, in the ionic liquid remain in the separatory funnel, for collecting the lower saturated aqueous solution. (6) to the above-mentioned is the ionic liquid solution to add a new configuration of the separatory funnel in NaBF 4 saturated aqueous solution 20 ml, fully after shaking, static hierarchical. Separating processing, the ionic liquid solution in the separatory funnel, for collecting liquid, so repeat two; (7) of the above-mentioned ionic liquid solution after washing transferred to the 250 ml round-bottom flask in grinding port, the magnetic stirring, 80 o C and 0.1 Pa vacuum drying under the conditions of 10 hours, filtering after standing, shall be 90g nocolor ionic liquid BMImBF 4, the yield is 80%. (8) in the above-mentioned step (4) the resulting solid inorganic salt by-product filter NaCl, new configuration for NaCl saturated aqueous solution of washing 3 times, each time the amount of 50 ml; (9) the above-mentioned inorganic salt NaCl transfer to 50 ml beaker, in 80 o C and 0.1 Pa dried in vacuum oven for 10 hours, to obtain 20g white solid NaCl, for the recovery of by-products 70%; (10) of step (5) collection of the lower saturated aqueous solution and step (6) of the collected liquid to be mixed to be mixed, mixed solution is mainly containing anion precursor saturated aqueous solution of inorganic salts, can be used repeatedly, that is, repeating the above-mentioned step (2), (3), (4), (5), (6), (7), (8), (9). |
In water; for 24h; | Preparation of 1-butyl-3-methylimidazolium tetrafluoroborate; Methylimidazole and excessive amount of chloro-n-butane (molar ratio: 1/1.05) were reacted at 70 C. with stirring for 48 hours. Excessive of reactants were removed by rotary evaporation, thereby 1-butyl-3-methylimidazolium chloride was obtained. The obtained 1-butyl-3-methylimidazolium chloride was further added into an aqueous solution with excessive amount of sodium tetrafluoroborate (molar ratio: 1/1.1) and stirred for 24 hours. Then, adequate amount of methylene dichloride was added to extract the product. A mixture of the product and the methylene dichloride was washed with water until no chlorine ion was detected by a silver nitrate solution (0.1 mol/L). A product of 1-butyl-3-methylimidazolium tetrafluoroborate was obtained after removing methylene dichloride in the product by rotary evaporation and drying. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogenchloride; In ethanol; water; at 20℃; for 18h;Product distribution / selectivity; | Removal of the Boc group was accomplished as described in General Method A. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hafnium tetrachloride; at 15 - 200℃; | 1 M of HfCI4 is dissolved into BMIM+BF4" ionic liquid. Solution precursor is delivered at 150C and 5O0C to a vaporizer that operates at a temperature between 6O0C and 2000C. HfCI4 precursor in vapor phase exits the vaporizer and is delivered into the reaction chamber. The ionic liquid remains in liquid state and is captured at the bottom of the vaporizer where it can be removed through a drain. The captured ionic liquid may be recycled and reused in making new precursor solutions. At the reaction chamber, HfCI4 precursor reacts with either oxygen or nitrogen containing vapor reagents to form a layer of HfO2 or HfNx material for high-K/metal gate applications. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N,N-tetraethylammonium tetrafluoroborate; In N,N-dimethyl-formamide; at 25℃;Inert atmosphere; Electrolysis; | General procedure: Catholyte (0.10molL-1 of ionic liquid 1a-h in 5.0mL of organic solvent) and anolyte (2.0mL same solvent/electrolyte) were separated through a porous glass frit filled with methylcellulose in DMF-Et4N-BF4. The electrolysis was carried out, under N2 atmosphere at 25C, at a constant current (J=15mA·cm-2). After the consumption of 31C, the current was switched off, the anodic compartment removed and the catholyte analyzed by cyclic voltammetry at different time intervals from the end of the electrolysis | |
In N,N-dimethyl-formamide; at 25℃;Electrolysis; Inert atmosphere; | Catholyte (1.0 mmol of BMIm-BF4 1a in 3.0 mL of organicsolvent) and anolyte (2.0 mL same solvent/electrolyte) wereseparated through a porous plugfilled with methylcellulose inDMF-Et4N-BF4. The electrolysis was carried out, under N2atmosphere at 25 C, at a constant current (J = 15 mA cm2).After the consumption of 31 C, the current was switched off.Cinnamaldehyde 4 (0.5 mmol) and trifluoromethylacetophenone 5(1.5 mmol) were added to the catholyte immediately or after40 minutes (in which the catholyte was kept under nitrogen atroom temperature) and the mixture was stirred at 60 C for 2 h andat r.t. for 12 h.The solvent was evaporated under reduced pressure and theresidue extracted with Et2O (3 20 mL). The ethereal layers werecombined, the solvent was removed and the crude reactionmixture analyzed by 1H NMR. The mixture was purifed byflashchromatography, using n-hexane/ethyl acetate 95/5 as eluent toafford the pure 4,5-diphenyl-5-trifluoromethyl-g-butyrolactone 6in the yields reported in Table 1. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 300℃; for 0.0333333h;Microwave irradiation; | [00021] Nanoparticulate MgF2 was formed by combining 10 grams (g) of a room-temperature ionic liquid solvent, l-butyl-3-methylimidazolium tetrafluoroborate (BMIBF4, Solvent Innovation GmbH) and 1 g of magnesium acetate tetrahydrate precursor salt (Acros Organics). The mixture was heated in a MW oven (2.45 gigahertz, Kenwood 900 Watt) for 2 minutes. The temperature of the reaction mixture reached approximately 300 degrees Celsius (C). At the end of the reaction, the solid nanoparticulate products were washed several times with acetonitrile, methanol and then double-distilled water to remove the ionic liquid and organic impurities. The washed nanoparticles were then dried under vacuum. [00022] The same procedure was used to coat glass surfaces with nanoparticles, however, glass slides formed by cutting standard microscope glass slides, were added directly into the chemical reaction medium. After the reaction in the MW, the glass slides were washed several times with methanol and double distilled water to remove the ionic liquid and organic impurities. [00023] The nanoparticles were determined to have an average diameter of about 30 nm calculated from X-ray diffraction patterns using the Debye-Scherrer equation and based on dynamic light scattering measurements. Size of the particles was also determined using transmission electron microscopy to have a size of 20-25 nm. The nanoparticles were analyzed using powder X-ray diffraction and were determined to be crystalline tetragonal MgF2. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
11%; 89% | The NHC-BMIm-BF4 or NHC-CO2-BMIm-BF4 solution was added to 0.5mmol of elemental sulfur and the mixture subjected to ultrasound irradiation (4W) for 10min. Then usual workup [49] gave the product in the yields reported in Table 1. | |
12%; 11% | The NHC-BMIm-BF4 or NHC-CO2-BMIm-BF4 solution was added to 0.5mmol of elemental sulfur and the mixture subjected to ultrasound irradiation (4W) for 10min. Then usual workup [49] gave the product in the yields reported in Table 1. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
11% | The NHC-BMIm-BF4 or NHC-CO2-BMIm-BF4 solution was added to 0.5mmol of elemental sulfur and the mixture subjected to ultrasound irradiation (4W) for 10min. Then usual workup [49] gave the product in the yields reported in Table 1. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
A galvanostatic electrolysis was carried out on BMIm-BF4 (catholyte: 2ml; anolyte: 1ml) under N2 atmosphere at 60C. The current density was 20mAcm-2. After 97C, the current was switched off, the anodic compartment removed and the catholyte kept as it was (obtaining the NHC-BMIm-BF4 solution) or CO2 was bubbled into the catholyte for 15min (obtaining the NHC-CO2-BMIm-BF4 solution). The two solutions were kept at room temperature under air for the time reported in Table 1 or used immediately after their preparation (Tables 2 and 3). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
94% | With selenium; potassium carbonate; In ethanol; for 3h;Reflux; | General procedure: 1-Butyl-3-methylimidazolidine, chloride salt (5 mmol), selenium (5 mmol), potassium carbonate (10 mmol), ethanol or acetone (5 mL) and a magnetic stirring bar were placed in a 50 mL, two-necked flask. Then the reaction mixture was vigorously stirred under reflux for the given times (see Table 2). After the reaction was complete, the resultant mixture was filtered, and the solvent evaporated under reduced pressure. Further purification by column chromatography on silica gel gave the pure product. All the products were characterised by NMR and HRMS. |
74% | With selenium; sodium carbonate; In water; for 4h;Reflux; | General procedure: In a 50-mL, two-necked flask, 1-butyl-3-methylimidazolium chloride (5 mmol), selenium (5 mmol), Na2CO3 (10 mmol), H2O (5 mL), and a magnetic stirring bar were placed. Then, the reaction mixture was vigorous stirring under refluxing condition for 4 h. After the reaction was complete, and the resultant mixture was filtered, and the solvent evaporated under reduced pressure. Further purification by recrystallization or column chromatography on silica gel gave the pure product. All the products were characterized by NMR and HRMS. Detailed characterization of the previously known compounds from Table 2 arepresented in the Supplemental Materials. |
Tags: 174501-65-6 synthesis path| 174501-65-6 SDS| 174501-65-6 COA| 174501-65-6 purity| 174501-65-6 application| 174501-65-6 NMR| 174501-65-6 COA| 174501-65-6 structure
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P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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