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Chemical Structure| 17430-71-6 Chemical Structure| 17430-71-6

Structure of 17430-71-6

Chemical Structure| 17430-71-6

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Product Details of [ 17430-71-6 ]

CAS No. :17430-71-6
Formula : C16H22O12
M.W : 406.34
SMILES Code : [C@H]([C@@H]([C@@H](OC(C)=O)C(O)=O)OC(C)=O)([C@@H](COC(C)=O)OC(C)=O)OC(C)=O
MDL No. :N/A

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Application In Synthesis of [ 17430-71-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 17430-71-6 ]

[ 17430-71-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 17430-71-6 ]
  • [ 125414-41-7 ]
  • C40H57NO26 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With pyridine; dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; for 12h; A solution of pentaacetylated gluconic acid (2.08 eq.) in anhydrous DCM is treated with EDC1 (2.2 eq.) and pyridine (3.4 eq.). <strong>[125414-41-7]N-Boc-serinol</strong> (1.0 eq.) is added into the reaction mixture followed by addition of DMAP (catalytic amount). The reaction mixture is stirred for 12 hours and is poured into saturated aq. ammonium chloride solution. The organic phase is separated and extracted with DCM, dried over MgS04 and concentrated under reduced pressure to give a sticky solid. Flash column chromatography on silica eluting with 2 % methanol/DCM gives N-Boc-protected bis-acetylated gluconate ester as a colorless dense oll.
 

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