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Chemical Structure| 1659-75-2 Chemical Structure| 1659-75-2

Structure of 1659-75-2

Chemical Structure| 1659-75-2

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Product Details of [ 1659-75-2 ]

CAS No. :1659-75-2
Formula : C14H22O4
M.W : 254.32
SMILES Code : CCOC(=O)C12CCC(CC1)(CC2)C(=O)OCC
MDL No. :MFCD18252888

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Application In Synthesis of [ 1659-75-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1659-75-2 ]

[ 1659-75-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1659-75-2 ]
  • [ 826-45-9 ]
YieldReaction ConditionsOperation in experiment
88% With lithium aluminium tetrahydride; In diethyl ether; for 4.0h;Inert atmosphere; Reflux; A solution of 12 (3.0313 g 11.91 mmol) in ether was added to a suspension of LiAlH4 (856.9 mg, 23.84 mmol) in ether under Ar atmosphere, and the mixture was refluxed for 4 h. The reaction was quenched by slow addition of 2 M sodium hydroxide and water. The mixture was filtered and the salt was washed with ether. The ether layer was combined, dried over Na2SO4 and concentrated to afford 13 (1.7899 g, 88percent). 1H-NMR (600 MHz, CDCl3) 1.43 (s, 14 H), 3.27 (s, 4 H).
 

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