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Chemical Structure| 15672-88-5 Chemical Structure| 15672-88-5

Structure of 15672-88-5

Chemical Structure| 15672-88-5

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Product Details of [ 15672-88-5 ]

CAS No. :15672-88-5
Formula : C6H13I
M.W : 212.07
SMILES Code : CC(C)(C)CCI
MDL No. :MFCD06797756

Safety of [ 15672-88-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H302-H315-H319-H335
Precautionary Statements:P210-P233-P235+P410-P240-P241-P242-P243-P260-P264-P270-P271-P280-P301+P312-P301+P330+P331-P302+P352-P304+P340-P305+P351+P338-P309+P311-P362-P370+P378-P403+P233-P403+P235
Class:3
UN#:1993
Packing Group:

Application In Synthesis of [ 15672-88-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 15672-88-5 ]

[ 15672-88-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 15672-88-5 ]
  • [ 21642-98-8 ]
  • [ 1126652-32-1 ]
YieldReaction ConditionsOperation in experiment
With potassium carbonate; In acetonitrile; at 20℃; for 48.0h;Heating / reflux; To a stirred solution of 4-methoxy-2-oxo-1,2-dihydro-2-pyridine carbonitrile (20 mmol) in anhydrous acetonitrile (100 ml), was added potassium carbonate (30 mmol) under nitrogen. Intermediate 10 (26 mmol) diluted in acetonitrile (50 ml) was then added at room temperature. The reaction mixture was refluxed for 2 days. Acetonitrile was removed under reduced pressure. Water (100 ml) and ethyl acetate (200 ml) were added. The organic phase was extracted, dried over Na2SO4, filtered and evaporated. The crude material was purified by chromatography on silica gel to give intermediate 58, which was a white solid. Intermediate 58 was characterized by the following spectroscopic data: 1H NMR (CDCl3, 400 MHz) (ppm) 0.99 (s, 9H), 1.57-1.61 (m, 2H), 3.91-3.95 (m, 2H), 3.99 (s, 3H), 6.09 (d, J=7.68 Hz, 1H), 7.53 (d, J=7.68 Hz, 1H); and MS (ESI, EI+) m/z=335(MH+).
 

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