Home Cart Sign in  
Chemical Structure| 14047-53-1 Chemical Structure| 14047-53-1

Structure of 14047-53-1

Chemical Structure| 14047-53-1

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 14047-53-1 ]

CAS No. :14047-53-1
Formula : C6H7NO2
M.W : 125.13
SMILES Code : OCC1=NC=CC=C1O
MDL No. :MFCD00128114

Safety of [ 14047-53-1 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H303-H315-H318-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P310-P321-P332+P313-P362-P403+P233-P501

Application In Synthesis of [ 14047-53-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14047-53-1 ]

[ 14047-53-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14047-53-1 ]
  • [ 14173-30-9 ]
YieldReaction ConditionsOperation in experiment
1.57 g With hydrogenchloride; In acetone; A mixture of 3-(hydroxymethyl)pyridine (3.00 g, 31.5 mmol), sodium hydroxide (1.26 g, 31.5 mmol), and 37% aqueous solution of formaldehyde (3.00 g, 37.0 mmol) in water (15 mL) was heated for 3 h at 90 C. Then, the reaction mixture was cooled to ~20 C and neutralized by the addition of glacial acetic acid. A solution obtained was dried in vacuo. The dry residue was extracted with boiling acetone (200 mL), the insoluble part was filtered off, whereas gaseous hydrogen chloride was passed through the filtrate. A precipitate formed was filtered off. The yield was 1.57 g (31%), a white crystalline compound, m.p. 212- 216 C (cf. Ref. 33: m.p. 213-216 C). 1H NMR (DMSO-d6), d: 4.77 (s, 2 H, CH2OH); 6.45 (br.s, 1 H, CH2OH); 7.75 (dd, 1 H, 5-PyH, J1= 8.4 Hz, J2= 5.4 Hz); 8.12 (d, 1 H, 4-PyH, J = 8.4 Hz); 8.20 (d, 1 H, 6-PyH, J = 5.4 Hz); 12.36 (br.s, 1 H, OH). 13C NMR (DMSO-d6), d: 56.22 (s, CH2O); 125.84 (s, CPyr); 129.37 (s, CPyr); 131.16 (s, CPyr); 144.72 (s, CPyr); 153.22 (s, CPyr).
 

Historical Records

Technical Information

Categories

Similar Product of
[ 14047-53-1 ]

Chemical Structure| 14173-30-9

A397295 [14173-30-9]

3-Hydroxy-2-pyridinemethanol hydrochloride

Reason: Free-salt