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Chemical Structure| 139102-37-7 Chemical Structure| 139102-37-7

Structure of 139102-37-7

Chemical Structure| 139102-37-7

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Product Details of [ 139102-37-7 ]

CAS No. :139102-37-7
Formula : C8H7IO2
M.W : 262.04
SMILES Code : O=CC1=CC=C(I)C=C1OC
MDL No. :MFCD20924440
InChI Key :ZDNOHFJWXJKIJF-UHFFFAOYSA-N
Pubchem ID :15128239

Safety of [ 139102-37-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P261-P280-P305+P351+P338-P304+P340

Application In Synthesis of [ 139102-37-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 139102-37-7 ]

[ 139102-37-7 ] Synthesis Path-Downstream   1~33

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  • [ 89942-34-7 ]
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  • [ 1196-65-2 ]
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  • [ 79-24-3 ]
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  • [ 139102-30-0 ]
  • 7
  • [ 625-82-1 ]
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  • C20H22BF2IN2O [ No CAS ]
  • 8
  • [ 16870-28-3 ]
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  • [ 1260102-33-7 ]
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  • [ 1260102-20-2 ]
  • 13
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  • C25H31BF2N2OSi [ No CAS ]
  • 15
  • [ 38170-02-4 ]
  • [ 74-88-4 ]
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  • 16
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  • [ 1374859-01-4 ]
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  • C22H23N3O4S [ No CAS ]
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  • [ 1374859-03-6 ]
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  • C19H19N3O4S [ No CAS ]
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  • C21H21N3O4S [ No CAS ]
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  • C23H25N3O4S [ No CAS ]
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  • [ 139102-37-7 ]
  • C22H23N3O4S [ No CAS ]
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  • C30H32N4O4S [ No CAS ]
  • C30H32N4O4S [ No CAS ]
  • 24
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  • [ 1374858-38-4 ]
  • 25
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  • C22H24N4O3S [ No CAS ]
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  • [ 1374858-45-3 ]
  • 27
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  • copper(l) cyanide [ No CAS ]
  • [ 21962-45-8 ]
  • 28
  • [ 139102-37-7 ]
  • [ 292638-85-8 ]
  • C12H12O4 [ No CAS ]
  • 29
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  • boronate ester [ No CAS ]
  • [ 1374858-61-3 ]
  • 30
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  • 4-(9H-carbazol-9-yl)-2-hydroxybenzaldehyde [ No CAS ]
  • 31
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  • 3-(benzo[d]thiazol-2-yl)-7-(9H-carbazol-9-yl)-2H-chromen-2-one [ No CAS ]
  • 32
  • [ 139102-37-7 ]
  • [ 86-74-8 ]
  • 4-(9H-carbazol-9-yl)-2-methoxybenzaldehyde [ No CAS ]
YieldReaction ConditionsOperation in experiment
46% With 18-crown-6 ether; copper; potassium carbonate; In 1,2-dichloro-benzene; at 200℃; for 0.333333h;Microwave irradiation; To a magnetically stirred solution of carbazole (0.89 mmol)i n 1 , 2 - d i c h l o r o be n z ene ( 0 . 2 ml ) 4 - i o do- 2 -methoxybenzaldehyde 3 (0.89 mmol), K2CO3 (2.67 mmol),Cu (0.44 mmol) and 18-crown-6 (1.78 mmol) were added in10 ml microwave tube. The mixture was degassed with nitrogenfor about 30 min and then heated at 200 C for 20 min inthe microwave. The temperature of the reaction mixture wasbrought down, filtered and evaporated giving a brown oil which was treated with hexane and left overnight with constant magneticstirring to elute impurities. The hexane layer wasdiscarded and the residue was purified by column using hexane:ethyl acetate (10:1) as an eluent. Yield 46%. Mp. 138-140 C.1H NMR (500 MHz, CdCl3) δ 10.51 (s, 1H), 8.14 (d, J =7.7 Hz, 2H), 8.07 (d, J = 8.2Hz, 1H), 7.52 (d, J = 8.2 Hz, 2H),7.45-7.42 (m, 2H), 7.34-7.30 (m, 2H), 7.29 (dd, J = 8.2,1.2 Hz, 1H), 7.23 (d, J = 1.7 Hz, 1H), 3.96 (s, 3H).13C NMR (126 MHz, CdCl3) δ 188.66, 162.90, 144.68,140.02, 130.21, 126.27, 123.90, 123.39, 120.72, 120.49,118.73, 109.89, 109.67, 56.02.
  • 33
  • [ 38170-02-4 ]
  • DMS [ No CAS ]
  • [ 139102-37-7 ]
YieldReaction ConditionsOperation in experiment
40% With sodium carbonate; In acetone; for 12h;Inert atmosphere; Reflux; Under nitrogen, <strong>[38170-02-4]2-hydroxy-4-iodobenzaldehyde</strong>(0.093 mmol) and sodium carbonate (2.8 mmol) were takenin RB flask with acetone to it DMS (1.8 mmol) was added.The reaction mixture was refluxed for 12 h. After completionof reaction, sodium carbonate was filtered out. The remainingsolution was concentrated on rota evaporator. Yield: 40%.Mp. 84-86 C. 1H NMR (500 MHz, CdCl3) delta 10.41 (s, 1H), 7.51 (d, J =8.1 Hz, 1H), 7.42 (ddd, J = 8.2, 1.3, 0.7 Hz, 1H), 7.37 (d, J =1.3 Hz, 1H), 3.93 (s, 3H).
 

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Technical Information

• Alkyl Halide Occurrence • Barbier Coupling Reaction • Baylis-Hillman Reaction • Benzylic Oxidation • Birch Reduction • Blanc Chloromethylation • Bucherer-Bergs Reaction • Clemmensen Reduction • Complex Metal Hydride Reductions • Corey-Chaykovsky Reaction • Corey-Fuchs Reaction • Fischer Indole Synthesis • Friedel-Crafts Reaction • General Reactivity • Grignard Reaction • Hantzsch Dihydropyridine Synthesis • Henry Nitroaldol Reaction • Hiyama Cross-Coupling Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Hydrogenolysis of Benzyl Ether • Julia-Kocienski Olefination • Kinetics of Alkyl Halides • Knoevenagel Condensation • Leuckart-Wallach Reaction • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Mukaiyama Aldol Reaction • Nomenclature of Ethers • Nozaki-Hiyama-Kishi Reaction • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Aldehydes and Ketones • Preparation of Alkylbenzene • Preparation of Amines • Preparation of Ethers • Prins Reaction • Reactions of Aldehydes and Ketones • Reactions of Alkyl Halides with Reducing Metals • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions of Dihalides • Reactions of Ethers • Reformatsky Reaction • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Stetter Reaction • Stobbe Condensation • Substitution and Elimination Reactions of Alkyl Halides • Suzuki Coupling • Tebbe Olefination • Ugi Reaction • Vilsmeier-Haack Reaction • Wittig Reaction • Wolff-Kishner Reduction

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