Structure of Sodium 4-chlorophenoxyacetate
CAS No.: 13730-98-8
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CAS No. : | 13730-98-8 |
Formula : | C8H6ClNaO3 |
M.W : | 208.57 |
SMILES Code : | O=C([O-])COC1=CC=C(Cl)C=C1.[Na+] |
MDL No. : | MFCD01743486 |
InChI Key : | CETFXLWWGIUWAI-UHFFFAOYSA-M |
Pubchem ID : | 23675789 |
GHS Pictogram: |
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Signal Word: | Warning |
Hazard Statements: | H302-H315-H319-H332-H335 |
Precautionary Statements: | P261-P280-P305+P351+P338 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
2083.1 g | With sodium hydroxide; at 120℃; for 3.0h;Large scale; | To the obtained isooctyl 4-chlorophenoxyacetate, 790.2 g of 50% sodium hydroxide was added, and the reaction was carried out at 120 C for 3 h.At the same time, the alcohol formed by the reaction is distilled off, the reaction is cooled down to room temperature, and the filter cake is dried.2083.1g of 4-chlorophenoxyacetic acid sodium salt, the content is 98.9%,The total yield was 98.77% based on phenol. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
209.15 g | With sodium hydrogencarbonate; In water; at 80℃; for 2.0h; | To the obtained methyl 4-chlorophenoxyacetate, 87.07 g of 99% sodium hydrogencarbonate and 129.30 g of water were added, and the mixture was reacted at 80 C for 2 h.At the same time, the alcohol formed by the reaction is distilled off, and the reaction is cooled down to room temperature for filtration.The filter cake is dried to obtain 209.15 g of sodium 4-chlorophenoxyacetate, and the content is 98.6%.The total yield was 98.86% based on phenol. |