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Chemical Structure| 13669-65-3 Chemical Structure| 13669-65-3

Structure of 13669-65-3

Chemical Structure| 13669-65-3

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Product Details of [ 13669-65-3 ]

CAS No. :13669-65-3
Formula : C9H5BrClN
M.W : 242.50
SMILES Code : ClC1=CC=C2N=CC(Br)=CC2=C1
MDL No. :MFCD18253965
InChI Key :VIPZVVMRXUNRAT-UHFFFAOYSA-N
Pubchem ID :15378465

Safety of [ 13669-65-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 13669-65-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13669-65-3 ]

[ 13669-65-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 13669-65-3 ]
  • [ 538-28-3 ]
  • 6-chloro-3-phenylmethylsulfanylquinoline [ No CAS ]
YieldReaction ConditionsOperation in experiment
89% A mixture of S-benzyl-isothiouronium chloride (305 mg, 1.5mmol), NaOH (200 mg, 5 mmol),and dry DMF (10 mL) was heated with stirring at 80 C under an argon atmosphere for 1 h. Then,6-chloro-3-bromoquinoline (7) (242 mg, 1 mmol) was added, and heating and stirring continued for 6 h.The mixture was cooled to room temperature and poured into ice water (80 mL). The solid was filteredoff, washed with water, and air-dried. 6-Chloro-3-phenylmethyl-sulfanylquinoline was recrystallizedfrom a mixture of hexane?CH2Cl2 (7:3, v/v) to give pure compound (10) (89percent). m.p. 77?78 °C (lit. m.p.77?78 °C [34]).
 

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Related Functional Groups of
[ 13669-65-3 ]

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Related Parent Nucleus of
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