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Chemical Structure| 13466-78-9 Chemical Structure| 13466-78-9
Chemical Structure| 13466-78-9

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3-Carene is a bicyclic monoterpene which occurs naturally as a constituent of turpentine.

Synonyms: (±)-Δ3-Carene; Delta-3-Carene; (±)-3-Carene

4.5 *For Research Use Only !

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Product Details of 3-Carene

CAS No. :13466-78-9
Formula : C10H16
M.W : 136.23
SMILES Code : CC1(C)C2CC=C(C)CC21
Synonyms :
(±)-Δ3-Carene; Delta-3-Carene; (±)-3-Carene
MDL No. :MFCD00001315
InChI Key :BQOFWKZOCNGFEC-UHFFFAOYSA-N
Pubchem ID :26049

Safety of 3-Carene

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H304-H315-H317-H412
Precautionary Statements:P210-P233-P240-P241-P242-P243-P261-P264-P272-P273-P280-P301+P310-P303+P361+P353-P331-P333+P313-P362-P370+P378-P403+P235-P405-P501
Class:3
UN#:2319
Packing Group:

Application In Synthesis of 3-Carene

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13466-78-9 ]

[ 13466-78-9 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 13466-78-9 ]
  • [ 1197-01-9 ]
  • [ 81800-50-2 ]
  • [ 98-55-5 ]
  • [ 5208-37-7 ]
  • [ 67670-71-7 ]
  • [ 107493-44-7 ]
  • 2
  • [ 422-64-0 ]
  • [ 13466-78-9 ]
  • 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl 2,2,3,3,3-pentafluoropropanoate [ No CAS ]
  • 2-(3-methylcyclohex-3-en-1-yl)propan-2-yl 2,2,3,3,3-pentafluoropropanoate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzene; at 0 - 5℃; for 168h; General procedure: A solution of 5.0 g (0.037 mol) of 3-carene in 15 mL of benzene was cooled to 0°C, 4.2 g (0.037 mol) of trifluoroacetic acid was slowly added, and the mixture was kept for 7 days at 3?5°C. Samples of the reaction mixture were withdrawn intermittently and analyzed by 1H and 19F NMR. When the reaction was complete, the mixture was washed in succession with 20 mL of water, 20 mL of a 5percent solution of sodium hydrogen carbonate, and 20 mL of a 5percent solution of sodium chloride. The organic layer was dried over MgSO4 and evaporated on a rotary evaporator, and the residue was distilled under reduced pressure to isolate 3.6 g (39percent) of isomer mixture 3a/3b (1 : 0.7) as a colorless mobile liquid, bp 46?48°C (0.5 mm), nD22 = 1.4230. IR spectrum, nu, cm?1: 1776 (C=O), 1219 (C?F).
 

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