Home Cart Sign in  
Chemical Structure| 131738-73-3 Chemical Structure| 131738-73-3

Structure of 131738-73-3

Chemical Structure| 131738-73-3

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 131738-73-3 ]

CAS No. :131738-73-3
Formula : C9H11BrO
M.W : 215.09
SMILES Code : CC(OC1=CC(Br)=CC=C1)C
MDL No. :MFCD00070756
Boiling Point : No data available
InChI Key :JYWJZIQSPRFCDB-UHFFFAOYSA-N
Pubchem ID :3260801

Safety of [ 131738-73-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 131738-73-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 131738-73-3 ]

[ 131738-73-3 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 131738-73-3 ]
  • [ 75792-33-5 ]
YieldReaction ConditionsOperation in experiment
100% With n-butyllithium; In tetrahydrofuran; hexane; ethyl acetate; N,N-dimethyl-formamide; EXAMPLE 257A Preparation of 3-iso-propyloxybenzaldehyde A solution of 1-bromo-3-iso-propyloxybenzene (2.16 g, 10 mmol) in dry THF (30 mL) was cooled to -78 C. and n-BuLi (4.8 mL of a 2.5 m solution in hexane, 12 mmol) was added. The resulting solution was stirred 0.5 hours and DMF (7.3 g, 10 mmol) was added at -78 C. The reaction solution was partitioned between ethyl acetate and water. The organic layer was washed with brine, dried (Na2SO4), filtered and concentrated under vacuum. Purification on silica gel with 25% ethyl acetate/hexane afforded the title compound (1.64 g, 100%). MS (DCI/NH3) m/z 182 (M+NH4)+.
  • 2
  • [ 180307-56-6 ]
  • [ 131738-73-3 ]
  • C21H31NO3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
99% With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; In acetonitrile; at 98℃; for 6.0h;Sealed tube; A mixture of 3-sopropoxy-brornobenzene (1.997 g, 1.0 equiv), N-Boc-4- vinylpiperidine (2.943 g, 1.5 equiv), Pd(OAc)? (167 mg, 0.08 equiv), and P(o-tol)3 (680 mg,024 equiv) in CH3CN- Et3N (1:1, 16 mL) was heated at 98 C for 6 h in a sealed vial After cooling to room temperature, the volatiles were removed in vacuo. To the residue, DCM was added, washed with water, brine, dried over Na2SO, filtered, and concentrated. The crude product was purified by column chromatography on silica gel with EtOAc/heptane (0-20%) as an eluent to give 3.1622 g (99%) of Intermediate L as a yellow oil.
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 131738-73-3 ]

Aryls

Chemical Structure| 6967-88-0

A501486 [6967-88-0]

1-Bromo-4-isopropoxybenzene

Similarity: 1.00

Chemical Structure| 1112210-82-8

A177265 [1112210-82-8]

1,3-Dibromo-5-isopropoxybenzene

Similarity: 0.97

Chemical Structure| 1235566-57-0

A151809 [1235566-57-0]

1-Bromo-3-isopropoxy-5-methoxybenzene

Similarity: 0.97

Chemical Structure| 60876-70-2

A552805 [60876-70-2]

1-Bromo-4-(tert-butoxy)benzene

Similarity: 0.94

Chemical Structure| 1035690-22-2

A330018 [1035690-22-2]

1-Bromo-3-cyclopropoxybenzene

Similarity: 0.94

Bromides

Chemical Structure| 6967-88-0

A501486 [6967-88-0]

1-Bromo-4-isopropoxybenzene

Similarity: 1.00

Chemical Structure| 1112210-82-8

A177265 [1112210-82-8]

1,3-Dibromo-5-isopropoxybenzene

Similarity: 0.97

Chemical Structure| 1235566-57-0

A151809 [1235566-57-0]

1-Bromo-3-isopropoxy-5-methoxybenzene

Similarity: 0.97

Chemical Structure| 60876-70-2

A552805 [60876-70-2]

1-Bromo-4-(tert-butoxy)benzene

Similarity: 0.94

Chemical Structure| 1035690-22-2

A330018 [1035690-22-2]

1-Bromo-3-cyclopropoxybenzene

Similarity: 0.94

Ethers

Chemical Structure| 6967-88-0

A501486 [6967-88-0]

1-Bromo-4-isopropoxybenzene

Similarity: 1.00

Chemical Structure| 1112210-82-8

A177265 [1112210-82-8]

1,3-Dibromo-5-isopropoxybenzene

Similarity: 0.97

Chemical Structure| 1235566-57-0

A151809 [1235566-57-0]

1-Bromo-3-isopropoxy-5-methoxybenzene

Similarity: 0.97

Chemical Structure| 200875-37-2

A523900 [200875-37-2]

2-Bromo-6-isopropoxynaphthalene

Similarity: 0.94

Chemical Structure| 60876-70-2

A552805 [60876-70-2]

1-Bromo-4-(tert-butoxy)benzene

Similarity: 0.94