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Chemical Structure| 13107-53-4 Chemical Structure| 13107-53-4

Structure of 13107-53-4

Chemical Structure| 13107-53-4

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Product Details of [ 13107-53-4 ]

CAS No. :13107-53-4
Formula : C7H14O3
M.W : 146.18
SMILES Code : O=C(OCC)CCCCO
MDL No. :MFCD06204571

Safety of [ 13107-53-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 13107-53-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13107-53-4 ]

[ 13107-53-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 13107-53-4 ]
  • [ 1024594-86-2 ]
  • 5-ethoxy-5-oxopentyl-4,6-dibromothieno[3,4-b]thiophene-2-carboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With dmap; dicyclohexyl-carbodiimide; In dichloromethane; water; About 1.00 g (about 2.92 mmol) of <strong>[1024594-86-2]4,6-dibromothieno[3,4-b]thiophene-2-carboxylic acid</strong>, about 0.731 g (about 3.51 mmol) of dicyclohexylcarbodiimide (DCC), and about 0.123 g (about 1.01 mmol) of 4-dimethylaminopyridine (DMAP) are dissolved in about 10 ml of dichloromethane (MC) under nitrogen atmosphere, and about 2.19 g (about 15.0 mmol) of ethyl-5-hydroxypentanoate is added thereto. The mixture is agitated for about 20 hours at room temperature. Next, about 50 ml of water is poured to the agitated mixture, and the resulting mixture is extracted with dichloromethane. After the extraction, a small amount of water in an organic layer is removed with sodium sulfate, and a solvent therein is removed. The resulting product is purified through a column chromatography using silica gel, obtaining 5-ethoxy-5-oxopentyl-4,6-dibromothieno[3,4-b]thiophene-2-carboxylate. Then, an electron-donating polymer is prepared according to the following Reaction Scheme 4.
 

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