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Chemical Structure| 1288339-30-9 Chemical Structure| 1288339-30-9

Structure of 1288339-30-9

Chemical Structure| 1288339-30-9

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Product Details of [ 1288339-30-9 ]

CAS No. :1288339-30-9
Formula : C9H12N2
M.W : 148.21
SMILES Code : C1(C2CC2)=NNC(C3CC3)=C1

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Application In Synthesis of [ 1288339-30-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1288339-30-9 ]

[ 1288339-30-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1288339-30-9 ]
  • [ 847573-68-6 ]
  • (3S,6R,9S,12R,15S,18R,21S,24R)-6,18-bis[[4-(chloromethyl)phenyl]methyl]-3,9,15,21-tetraisobutyl-4,10,12,16,22,24-hexamethyl-1,7,13,19-tetraoxa-4,10,16,22-tetrazacyclotetracosane-2,5,8,11,14,17,20,23-octaone [ No CAS ]
  • C68H90N10O12 [ No CAS ]
YieldReaction ConditionsOperation in experiment
21% (1 a-13) was prepared: to a solution of Bis-CFhCI PF1022a (120 mg, 0.1 1 mmol) in acetonitrile (5.7ml_, 0.02M) was added 3,5-dicyclopropyl-1 H-pyrazole (25. 5 mg, 0.17 mmol, 1.5 equivalents), potassium bicarbonate (45.9 mg, 0.45 mmol) and potassium iodide (1 14mg, 0.69 mmol). The mixture was heated to 50C for 18 hours. 1 H- pyrazole-3,5-dicarbonitrile (34 mg, 0.28 mmol) was added and the mixture heated to 50C for 18 hours. After allowing cooling to room temperature, the solvent was removed under reduced pressure and the residue partitioned between water and DCM. The organics were separated, dried over MgS04 and evaporated. The crude material was purified by reverse phase HPLC to give the title product as a white solid (30mg, 21 %).
 

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