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Chemical Structure| 1257220-44-2 Chemical Structure| 1257220-44-2

Structure of 1257220-44-2

Chemical Structure| 1257220-44-2

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Product Details of [ 1257220-44-2 ]

CAS No. :1257220-44-2
Formula : C27H20BrN
M.W : 438.36
SMILES Code : CC(C1=CC(N(C2=CC=CC=C2)C3=C4C=C(Br)C=C3)=C4C=C15)(C)C6=C5C=CC=C6
MDL No. :MFCD24387260
InChI Key :NCEDTMHPBMLCOH-UHFFFAOYSA-N
Pubchem ID :66797663

Safety of [ 1257220-44-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 1257220-44-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1257220-44-2 ]

[ 1257220-44-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1255308-97-4 ]
  • [ 1257220-44-2 ]
  • C45H30N2S [ No CAS ]
YieldReaction ConditionsOperation in experiment
58% With potassium phosphate; copper(l) iodide; ethylenediamine; In toluene; at 120℃; for 22h; After mixing compound 1-4 (2-bromo-7,7-dimethyl-5-phenyl-indeno[2,1-b]carbazole) (7.5 g, 17 mmol), compound 3 (<strong>[1255308-97-4]5H-benzothiopheno[3,2-c]carbazole</strong>) (4.3 g, 15.5 mmol), CuI (1.5 g, 7.9 mmol), ethylenediamine (2 mL, 31 mmol), K3PO4 (10 g, 47 mmol) and toluene 90 mL in a 250 mL RBF, the mixture was stirred at 120C for 22 hours. The reaction mixture was worked up by EA/H2O, then the moisture was removed with MgSO4, and then distilled under reduced pressure. The crude product was purified by column chromatography with MC:hexane (Hx), and then recrystallized in toluene to obtain 5.7 g of white solid compound C-17 (58 %).
 

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