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Chemical Structure| 1233513-38-6 Chemical Structure| 1233513-38-6

Structure of 1233513-38-6

Chemical Structure| 1233513-38-6

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Product Details of [ 1233513-38-6 ]

CAS No. :1233513-38-6
Formula : C9H9NOS
M.W : 179.24
SMILES Code : N#CSCC1=CC(OC)=CC=C1
MDL No. :MFCD09025704
InChI Key :BAWQGDICORFTBO-UHFFFAOYSA-N
Pubchem ID :45040724

Safety of [ 1233513-38-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H332-H315-H319-H317-H334-H400
Precautionary Statements:P501-P261-P273-P272-P270-P271-P264-P280-P284-P302+P352-P391-P342+P311-P337+P313-P305+P351+P338-P362+P364-P333+P313-P301+P312+P330-P304+P340+P312
Class:9
UN#:3082
Packing Group:

Application In Synthesis of [ 1233513-38-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1233513-38-6 ]

[ 1233513-38-6 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 333-20-0 ]
  • [ 824-98-6 ]
  • [ 1233513-38-6 ]
YieldReaction ConditionsOperation in experiment
85% With Fe3O4*SiO2/DABCO; In water; at 90.0℃; for 1.0h; General procedure: To a suspension of alkyl halide (1 mmol) and nucleophilic reagents(NaOAc or KSCN) (2 mmol) in water (5 mL), Fe3O4SiO2/DABCO(0.225 g) was added and the mixture was stirred at 90 C for the lengths of time shown in Table 1. After completion of the reaction as indicated by TLC [using n-hexane/ethyl acetate (5:1)], the reaction was allowed to cool to room temperature and the magnetic catalyst was concentrated on the side wall of the reaction vessel using an external magnet. The reaction mixture residue was poured into water (10 mL)and extracted with EtOAc (3 × 10 mL). The combined organic layers were dried over anhydrous Na2SO4, filtered and evaporated in vacuo to give the product in 74% to 91% isolated yields.
  • 2
  • [ 540-72-7 ]
  • [ 824-98-6 ]
  • [ 1233513-38-6 ]
YieldReaction ConditionsOperation in experiment
84% With β-cyclodextrin-polyurethane polymercoated Fe3O4 magnetic nanoparticle; In water; at 90.0℃; for 0.583333h; General procedure: To a mixture of the benzyl halide (1.0 mmol) and MY (Y:N3, SCN, OAc, CN) (2 mmol) in water (5 ml), -CDPU-MNPs (0.1 g) was added. The suspension was magnetically stirred under reflux conditions for the time shown in Table 1. After complete consumption of starting material as judged by TLC (using n-hexane-ethylacetate as eluent), the catalyst was concentrated on the sidewall of the reaction vessel using an external magnet, the aqueous phase was separated by decantation and extracted with diethyl ether (2× 10 mL). The extracted was dried with calcium chloride (CaCl2) and evaporated in vacuo to give corresponding product. The residual catalyst in the reaction vessel was washed and dried and then subjected to the next run directly.
  • 3
  • [ 1147550-11-5 ]
  • [ 824-98-6 ]
  • [ 1233513-38-6 ]
  • 4
  • [ 333-20-0 ]
  • [ 874-98-6 ]
  • [ 1233513-38-6 ]
 

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