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Chemical Structure| 123291-15-6 Chemical Structure| 123291-15-6

Structure of 123291-15-6

Chemical Structure| 123291-15-6

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Product Details of [ 123291-15-6 ]

CAS No. :123291-15-6
Formula : C23H15Br2N
M.W : 465.18
SMILES Code : BrC1=CC(C2=CC(C3=CC=CC=C3)=CC(C4=CC=CC(Br)=C4)=N2)=CC=C1
MDL No. :MFCD28965551
InChI Key :JPXLPGXBVLWTLK-UHFFFAOYSA-N
Pubchem ID :59428691

Safety of [ 123291-15-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 123291-15-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 123291-15-6 ]

[ 123291-15-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 123291-15-6 ]
  • [ 56525-79-2 ]
  • C71H47N3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
69% A solution was prepared by stirring tris(dibenzylideneacetone)dipalladium(0) chloroform complex (0.104 g), tri(t-butyl)phosphine (0.162 g), and toluene (5 ml) under nitrogen atmosphere at 60°C for 10 min. This solution was added to a mixture heated to 60°C of 2,6-bis(3-bromophenyl)-4-phenylpyridine (1.30 g), <strong>[56525-79-2]3,6-diphenylcarbazole</strong> (2.68 g), t-butoxysodium (1.18 g), and toluene (25 ml) under nitrogen atmosphere, and the resulting mixture was stirred at 110°C for 8 hr. The mixture was allowed to cool to room temperature and concentrated, and methanol was added thereto. The resulting precipitate was collected by filtration and washed with a water/methanol mixture solution. The precipitate was purified by silica-gel column chromatography (n-hexane/toluene = 1/1) and washed with an N,N-dimethylformamide/ethanol mixture solution and a methylene chloride/methanol mixture solution and then dried under reduced pressure to obtain a target compound 24 (1.81 g, yield: 69percent) as a white crystal. This white crystal was purified by sublimation to yield 1.35 g of a white solid. The white solid was confirmed to be a target compound 24 by DEI-MS (m/z = 924 (M+)). The compound had a vaporization temperature of 570°C and a glass transition temperature of 172°C. The melting point was not observed.
  • 2
  • [ 123291-15-6 ]
  • [ 870119-58-7 ]
  • C59H39N3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With potassium carbonate;tetrakis(triphenylphosphine) palladium(0); In 1,2-dimethoxyethane; water; for 6h;Heating / reflux; To a mixture of the target compound 5 (1.86g), the target compound 12 (3.84 g), dimethoxyethane (80 ml), and water (12 ml), tetrakis(triphenylphosphine)palladium (0.37 g) and potassium carbonate (3.32 g) were sequentially added. The resulting mixture was stirred while heating under reflux for 6 hr. To the resulting solution, brine (100 ml) was added. After extraction with dichloromethane (2 x 100 ml), anhydrous magnesium sulfate and active clay were added to the organic layer. The mixture was stirred, filtered, and concentrated to obtain a solid content. The solid content was purified by silica-gel column chromatography to obtain a target compound 13 (2.16 g). The obtained compound was confirmed to be a target compound 13 by DEI-MS (m/z = 789 (M+)). The compound had a vaporization temperature of 541C and a glass transition temperature of 125C. The melting point was not detected.
 

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