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Chemical Structure| 122948-57-6 Chemical Structure| 122948-57-6

Structure of 122948-57-6

Chemical Structure| 122948-57-6

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Product Details of [ 122948-57-6 ]

CAS No. :122948-57-6
Formula : C10H13F3O5S
M.W : 302.27
SMILES Code : CCOC(=O)C1CCC(OS(=O)(=O)C(F)(F)F)=CC1
MDL No. :MFCD17169871

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Application In Synthesis of [ 122948-57-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 122948-57-6 ]

[ 122948-57-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 38222-83-2 ]
  • [ 17159-79-4 ]
  • [ 122948-57-6 ]
YieldReaction ConditionsOperation in experiment
With trifluorormethanesulfonic acid; In dichloromethane; at 25℃; (1) To a solution of 4-oxocyclohexanecarboxylic acid ethyl ester (8.0 g) and 2,6-di(tert-butyl)-4-methylpyridine (14.4 g) in dichloromethane (200 ml) is added trifluoromethanesulfonic anhydride (8.73 ml) at -78°C, and the mixture is gradually warmed to 25°C, and the mixture is stirred at the same temperature overnight.. The reaction solution is poured into aqueous sodium hydrogen carbonate solution, and the mixture is extracted with ethyl acetate.. The organic layer is washed with saturated brine, and the solvent is evaporated under reduced pressure to give 4-trifluoromethanesulfonyloxy-3-cyclohexenecarboxylic acid ethyl ester.
 

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