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Chemical Structure| 1220696-32-1 Chemical Structure| 1220696-32-1

Structure of 1220696-32-1

Chemical Structure| 1220696-32-1

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Product Details of [ 1220696-32-1 ]

CAS No. :1220696-32-1
Formula : C14H18BNO4
M.W : 275.11
SMILES Code : O=C1OC2=CC=C(B3OC(C)(C)C(C)(C)O3)C=C2N1C
MDL No. :MFCD18383775

Safety of [ 1220696-32-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 1220696-32-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1220696-32-1 ]

[ 1220696-32-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1220696-32-1 ]
  • [ 1227573-02-5 ]
  • [ 1255713-83-7 ]
YieldReaction ConditionsOperation in experiment
35% A mixture of 3-iVtelhyi-5-{4,4,5,5-tetraroethyi-(1 ,3,2]dioxabora.an-2-yl)-3H-benzalphaoxazoi-2- one (138 mg, 0,5 mmoi), 3-Bromo5~f1uoro~pyridine~4~carbafdehyde (102 mg, 0,5 mmoi), Na2CO3 (2 M in water, 0.75 mL, 1.5 mmoi) and PdCI2(PPh3)2 (17 mg, 0.03 mmoi) in DMF(3 mL) was heated at 1000C for 4 hrs. After concentration, the residue was diluted with DCM and saturated NH4C. solution. After filtration and concentration, the residue was purified by flash column (MeOH-C H2CI2, v/v, 0 - 1.5percent) and afforded the title compound (47 mg, 35percent). 1H NMR (400.3 MHz, CDCi3): S 3.45 (s, 3H), 6,96 (d, J = 1.7 Hz, 1H), 7.08 (dd, J = 8, 1.7 Hz, 1 H), 7.32 (d, J - 8 Hz, 1H), 8.59 (s, 1H), 8.68 (d, J - 1.3 Hz, I H), 10.07 (s, 1H),
 

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