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Chemical Structure| 1142-97-8 Chemical Structure| 1142-97-8

Structure of 1142-97-8

Chemical Structure| 1142-97-8

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Product Details of [ 1142-97-8 ]

CAS No. :1142-97-8
Formula : C12H9ClO2S2
M.W : 284.78
SMILES Code : O=S(C1=CC=CC=C1)(OC2=CC=C(Cl)C=C2)=S

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Application In Synthesis of [ 1142-97-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1142-97-8 ]

[ 1142-97-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14204-24-1 ]
  • [ 14752-66-0 ]
  • [ 1142-97-8 ]
YieldReaction ConditionsOperation in experiment
72% With scandium tris(trifluoromethanesulfonate); In water; at 30℃; for 6h;Ionic liquid; General procedure: To a solution of 1 (0.3 mmol) and 2 (0.36 mmol) in [BMIM]PF6 (3 mL) and H2O (1 mL), Sc(OTf)3 was added at 30 C. The mixture solution was stirred at 30 C for respective time. After the completion of the reaction, as monitored by TLC and GC-MS analysis, the mixture was washed with water and extracted with diethyl ether. The organic phase was concentrated and the resulting residue was purified by column chromatography on silica gel (300-400 mesh) with petroleum ether-EtOAc as eluent to provide the desired thiosulfonates 3.
 

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