Home Cart Sign in  
Chemical Structure| 1141757-83-6 Chemical Structure| 1141757-83-6

Structure of 1141757-83-6

Chemical Structure| 1141757-83-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 1141757-83-6 ]

CAS No. :1141757-83-6
Formula : C54H35N3
M.W : 725.88
SMILES Code : N1(C2=CC=CC=C2)C3=C(C4=C1C=CC=C4)C=C(C5=CC6=C(C=C5)N(C7=CC=CC=C7)C8=C6C=C(C9=CC%10=C(C=C9)N(C%11=CC=CC=C%11)C%12=C%10C=CC=C%12)C=C8)C=C3
InChI Key :FXKMXDQBHDTQII-UHFFFAOYSA-N
Pubchem ID :68185634

Safety of [ 1141757-83-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 1141757-83-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1141757-83-6 ]

[ 1141757-83-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1153-85-1 ]
  • [ 618442-57-2 ]
  • [ 1141757-83-6 ]
YieldReaction ConditionsOperation in experiment
82% (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) -9-phenylcarbazole,One equivalent (20 g, 40.49 mmol),3-Bromo-9-phenylcarbazole, 2Equivalent (26 g, 81 mmol), 33.5 g of K2CO3, 800 ml of toluene,And 200 ml of water was added to a 2-L 2-neck round bottom flask. The mixture was stirred at room temperature for 30 minutes,Pd (PPh3) 4 (1.4 g, 1.21 mmol) was added and refluxed for 24 hours.After the reaction was completed, the reaction mixture was extracted with methylene chloride, added with MgSO 4 and filtered.After removing the solvent of the obtained organic layer, it was purified by column chromatography to obtain intermediate compound 1 (24.80 g, yield 82%).
  • 2
  • [ 1126522-69-7 ]
  • [ 57103-20-5 ]
  • [ 1141757-83-6 ]
YieldReaction ConditionsOperation in experiment
60.9% With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In ethanol; water; toluene; for 5h;Reflux; Inert atmosphere; Synthesis Example 1 Synthesis of H1-1 compound: 1.6 g of 3,6-dibromo-9-phenyl-9oxazole, 2.4 g of 9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9Eta-carbazole under a nitrogen atmosphere ,0.23 g of tetrakis(triphenylphosphine)palladium, 6 ml of 2M aqueous potassium carbonate solution,20 ml of toluene and 5 ml of ethanol were placed in a reaction vessel, and then heated and stirred at reflux temperature for 5 hours.After cooling to 40 C, the insoluble material was removed by filtration, and the filtrate was concentrated under reduced pressure to give a crude product.The crude product was purified by recrystallization (solvent: toluene/methanol) and dried.1.76 g (yield: 60.9%) of 3,6-bis(9'-phenyl-9Eta-carbazol-3-yl)-9-phenyl-9H-carbazole (Compound H1-1) is obtained as a brownish white powder.
 

Historical Records

Technical Information

Categories